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Table 1 Approximate initial pore-water concentrations and direction of chemical gradients

From: 5-year chemico-physical evolution of concrete–claystone interfaces, Mont Terri rock laboratory (Switzerland)

Material

Age range

Ca2+

Mg2+

Na+

K+

SO4 2−

Cl

CO3 2−

OH

OPC

0.04–1310

24–2.9

<

26–90

137–209

66–4.5

<

~0.05

>200

ESDRED

0.04–1310

9.2-29

0–0.005

100–22

186–11

2–1.8

<

~0.05

180–7*

Gradient

 

OPA

 

12.7

14.3

204

2.3

11.8

237

~0.4

~10−7

  1. Concentrations in mmol/l; age range in days; < indicates below detection; first arrow (or pair) indicates direction of gradient at early time, second arrow at later times; long arrow is for ESDRED, short arrow for OPC
  2. aFormate is also significant as anionic charge carrier