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Table 5 Major and minor element composition of Ti-chondrodite and Ti-clinohumite

From: The role of the antigorite + brucite to olivine reaction in subducted serpentinites (Zermatt, Switzerland)

 

Ti-chondrodite

Ti-clinohumite

Sample

14

Ol1

14

FA

AF2

Ol1

MF

Ol26

Ol46

wt%

l

l

s

s

r

r

p

p

p

p

p

p

p

SiO2

32.95

33.14

33.66

33.68

37.48

37.26

37.76

37.39

37.26

37.48

38.53

37.27

37.85

TiO2

8.35

9.14

7.61

8.71

3.37

3.72

3.16

2.13

4.88

3.37

2.50

2.98

3.77

Al2O3

b.d.

0.03

0.01

0.01

b.d.

0.02

b.d.

0.01

0.14

b.d.

0.01

0.03

0.01

Cr2O3

0.01

0.02

0.01

b.d.

b.d.

b.d.

0.01

0.03

0.01

b.d.

0.01

b.d.

0.01

FeO

7.08

6.23

5.42

3.38

4.81

3.42

3.12

5.35

2.41

4.81

2.40

5.57

4.71

MnO

0.57

0.42

0.42

0.32

0.25

0.39

0.25

0.30

0.28

0.25

0.24

0.32

0.37

NiO

0.09

0.05

0.08

0.09

0.11

0.13

0.14

0.13

0.12

0.11

0.11

0.12

0.11

MgO

47.55

47.29

50.04

50.22

52.37

52.56

53.62

52.44

52.32

52.37

54.25

51.20

52.02

CaO

0.01

0.01

0.03

0.02

b.d.

b.d.

b.d.

b.d.

0.02

b.d.

b.d.

b.d.

0.02

H2O1

3.13

2.92

3.40

3.11

2.07

1.98

2.13

2.34

1.70

2.07

2.27

2.11

1.97

Total

99.74

99.25

100.72

99.53

100.46

99.49

100.19

100.16

99.14

100.46

100.33

99.65

100.86

Si

1.978

1.997

1.979

1.993

3.981

3.979

3.991

3.981

3.988

3.981

4.053

4.005

4.013

Ti

0.377

0.414

0.336

0.388

0.269

0.299

0.251

0.171

0.393

0.269

0.198

0.241

0.301

Al

0.002

0.001

< 0.001

0.003

0.002

0.017

0.002

0.003

0.001

Cr

0.001

0.001

< 0.001

0.001

0.003

0.001

0.001

0.001

Fe+2

0.355

0.314

0.267

0.167

0.427

0.305

0.276

0.476

0.216

0.427

0.211

0.501

0.418

Mn

0.029

0.022

0.021

0.016

0.022

0.035

0.022

0.027

0.026

0.022

0.022

0.029

0.034

Ni

0.004

0.003

0.004

0.004

0.010

0.012

0.012

0.011

0.010

0.010

0.009

0.010

0.009

Mg

4.255

4.247

4.386

4.430

8.291

8.367

8.447

8.323

8.348

8.291

8.506

8.201

8.221

Ca

< 0.001

0.001

0.002

0.001

0.002

0.003

H

1.255

1.173

1.334

1.228

1.466

1.407

1.500

1.662

1.217

1.466

1.593

1.515

1.396

Mg#

91.6

92.6

93.8

95.9

94.8

96.0

96.5

94.2

97.1

94.8

97.2

93.8

94.7

  1. Mg# = (Mg/(Mg + Fe + Ni + Mn))*100
  2. Ti-ch is normalized to 7 cations and 18 charges and Ti-cl on 13 cations and 34 charges
  3. l large grains (prograde first generation grains), s small grains (recrystallized), p prograde, r retrograde, b.d.  below detection limit
  4. 1H2O is recalculated from stoichiometry