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Unravelling the tectonic evolution of the Dinarides—Alps—Pannonian Basin transition zone: insights from structural analysis and low-temperature thermochronology from Ivanščica Mt., NW Croatia

Abstract

A comprehensive study, including geological mapping, structural and thermochronological analysis, has been carried out on Ivanščica Mountain (NW Croatia), with the aim to reconstruct the tectonic history of the Dinarides, Southern/Eastern Alps and Pannonian Basin transitional zone. Implementation of structural and thermochronological methods enabled a subdivision of Ivanščica Mt. into two structural domains (from bottom to top): Ivanščica Parautochthon and Ivanščica Imbricate Fan and Cenozoic sedimentary cover. In addition, a sequence of deformational events in tectonic history of this transitional zone is proposed, comprising three extensional and four contractional events starting from Middle Triassic until present times. The two oldest deformational events indicate Middle Triassic (D1) and Early Jurassic (D2) extensional pulses and only occur in volcano-sedimentary successions of the Ivanščica Mt. The oldest contractional event (D3) is related to the obduction of a Neotethyan ophiolitic mélange over an Upper Triassic to Lower Cretaceous succession of the eastern margin of the Adriatic microplate, which resulted in thermal overprint of the Ivanščica Imbricate Fan structural domain in Berriasian—Valanginian times (~ 140 Ma). This event was soon followed by a second contractional event (D4), which resulted in thrusting and imbrication of the Adriatic passive margin successions together with previously emplaced ophiolitic mélange, thermal overprint of the footwall successions, fast exhumation and erosion. Apatite fission track data together with syn-tectonic deposits indicate an Hauterivian to Albian age of this D4 event (~ 133–100 Ma). These Mesozoic structures were dextrally rotated in post-Oligocene times and brought from the initially typically Dinaridic SE striking and SW verging structures to the recent SW striking and NW verging structures. The following extensional event (D5) is associated with the formation of SE striking and mostly NE dipping normal listric faults, and ENE striking dextral faults accommodating top-NE extension in the Pannonian Basin. Deformations were coupled with hanging wall sedimentation of Ottnangian to middle Badenian (middle Burdigalian to upper Langhian; ~ 18–14 Ma) syn-rift deposit as observed from the reflection seismic and well data. A short-lasting contraction (D6) was registered in the late Sarmatian (late Serravallian; ~ 12 Ma). The youngest documented deformational event (D7) resulted in reactivation of ENE striking dextral faults, formation of SE striking dextral faults as well as the formation of E to ENE trending folds and reverse faults. This event corresponds to late Pannonian (late Messinian; ~ 6 Ma) to Present NNW-SSE contraction driven by the indentation and counterclockwise rotation of Adriatic microplate. Recognized tectonic events and their timings indicate that Ivanščica was mainly affected by deformational phases related to the Mesozoic evolution of the Neotethys Ocean as well as Cenozoic opening and inversion of the Pannonian Basin. Therefore, the Mesozoic tectono-sedimentary evolution of Ivanščica Mountain proves the paleogeographic affiliation of its non-ophiolitic Mesozoic structural-stratigraphic entities to the Pre-Karst unit of the Dinarides.

1 Introduction

Synchronous mountain building of neighbouring orogens often results in complex structural architectures and overprinting relationships. Such complex relationships can only be resolved by comprehensive studies that integrate lithostratigraphic, structural and thermochronological data obtained at local to regional scales of observations. In particular, such an approach is required in cases when both orogens are affected by post-orogenic extensional and/or strike-slip tectonics, a geodynamic scenario known from the past and at present in almost all peri-Mediterranean orogens (e.g., Meulenkamp et al., 1988; Jolivet & Faccenna, 2000; Faccenna et al., 2004, 2013; Kissling et al., 2006). This scenario, which commonly includes post-orogenic local- to regional-scale translations and rotations of differently sized tectonic blocks dismembered from previously formed collisional nappe stacks, is also known from the Dinarides—Alps—Pannonian Basin transitional zone (Fig. 1; e.g., Placer, 1999a; Haas et al., 2000; Tomljenović et al., 2008; van Gelder et al., 2015). This area records complex tectonic histories in the orogenic build-up of the Southern and Eastern Alps as well as the Dinarides, followed by several phases of extension and contraction in the tectonic evolution of the SW margin of the Pannonian Basin (e.g., Fodor et al., 1998; Vrabec & Fodor, 2006; Tomljenović & Csontos, 2001; van Gelder et al., 2015; Fodor et al., 2021). Here, Mesozoic formations of both Alps and Dinarides preserve records of geodynamic processes that resulted with opening and closure of the northern branch of the Neotethys Ocean (e.g., Pamić et al., 1998; Pamić, 2002; Schmid et al., 2008; 2020; Ustaszewski et al., 2010; the Balkan Neotethys sensu van Hinsbergen et al., 2020). In addition, the Alps record a separate and younger collisional event related to the closure of the Alpine Tethys Ocean (e.g., Neubauer et al., 1999; Willingshofer et al., 1999a; Schmid et al., 2008; 2020; van Hinsbergen et al., 2020). Both oceanic realms contemporaneously existed during a part of Mesozoic times, separating the Adria microplate from Eurasia (e.g., van Hinsbergen et al., 2020). However, during the time of their closure, which differs for each of these oceanic realms, the Adriatic microplate was in a different tectonic position with respect to the European plate: lower plate in the Dinarides and upper plate in the Alps (e.g., Doglioni et al., 1999; Schmid et al., 2008, 2020).

Fig. 1
figure 1

a Topographic map of the northern Adriatic realm. Note the red polygon representing outlines of Ivanščica Mt. b Tectonic map after Schmid et al. (2020) showing constituent tectonic units of the Dinarides and the Alps. Ivanščica Mt. (marked with yellow line) occupies position at the junction of the Western Vardar ophiolitic unit of the Dinarides and South Alpine unit of the Alps in the southwestern part of the Pannonian Basin (white outlines). PFS—Periadriatic Fault System. Location of figure is shown in a. c Geological map of the Ivanščica Mt. and wider surrounding area in the Dinarides—Alps—Pannonian Basin transitional zone (simplified and modified after Basic Geological Maps of former Yugoslavia on the 1:100,000 scale, sheets Celje (Buser, 1977), Rogatec (Aničić & Juriša, 1984), Varaždin (Šimunić et al., 1982), Novo Mesto (Pleničar et al., 1975), Zagreb (Šikić et al., 1977) and Ivanić (Basch, 1981)). Location of figure is shown in b

Due to the complex Mesozoic and Cenozoic geodynamics at the Dinarides-Southern/Eastern Alps-Pannonian Basin transitional zone (Fig. 1a, b), a detailed reconstruction of the tectonic and depositional history, in its part in the northern Croatia, is still lacking. Among several inselbergs in this area (Fig. 1c), Medvednica Mt. is the most comprehensively studied so far, providing a large data set on different topics regarding Mesozoic stratigraphy (e.g., Halamić et al., 1999, 2005; Babić et al., 2002, with references therein), metamorphic and igneous petrology (e.g., Belak & Tibljaš, 1998; Slovenec & Pamić, 2002; Lugović et al., 2007; Judik et al., 2008; Belak et al., 2022; Mišur et al., 2023;), paleomagnetism, structural architecture and tectonics (e.g., Tomljenović et al., 2008; van Gelder et al., 2015). The results of most of these studies, in combination with data from the Basic Geological Map of Yugoslavia, sheet Rogatec (Aničić & Juriša, 1984) and sheet Varaždin (Šimunić et al., 1982), were so far used for the correlation of pre-Neogene tectonic units in this transitional zone, only exposed in inselbergs, with corresponding tectonic units defined within a much wider surrounding area (e.g., Haas et al., 2000; van Gelder et al., 2015) and across the entire Alpine-Carpathian-Dinaridic-Hellenic orogenic system (e.g., Schmid et al., 2008, 2020; van Hinsbergen et al., 2020). Compared with the neighbouring Medvednica Mt., modern data on the geology of the Ivanščica Mt. were relatively scarce (Babić et al., 2002; Goričan et al., 2005; Lužar-Oberiter et al., 2009, 2012), until recently when a series of studies were released by the ‘GOST’ project (https://projectgost.wordpress.com). These studies provide new data set on stratigraphy (Slovenec et al., 2020; Kukoč et al., 2023, 2024), petrology (Slovenec & Šegvić, 2024; Slovenec et al., 2023; Šegvić et al., 2023) and lithostratigraphy of the Adriatic passive margin successions (Vukovski et al., 2023), tectonically assembled into the structural architecture of Ivanščica Mt.

Being a supplement to published studies of the GOST project, this paper aims to present new and more detailed data on the spatial arrangement, kinematics and age of deformational structures in Mesozoic and Cenozoic rocks of Ivanščica Mt. and neighbouring area. These data were obtained by a multi-scale structural analysis, including geological mapping, interpretation of reflection seismic sections, vitrinite reflectance and apatite fission track measurements. After a short overview on geological and structural setting of Ivanščica Mt. based on previously published data, this paper presents new data on the structural architecture and low-temperature thermochronology of the study area.

These data are then used to propose a sequence of deformational events in the study area. The presented deformational sequence is correlated with deformational events revealed in neighbouring areas of the Dinarides, Southern and Eastern Alps and SW Pannonian Basin. Obtained deformational events are discussed in the context of tectonic evolution of the region, starting from the Middle Triassic until present. Finally, we propose a new correlation between the established tectonic units of Ivanščica Mt. with those known from the Internal Dinarides.

2 Geological setting of Ivanščica Mountain

Ivanščica Mt. is built by upper Paleozoic and Mesozoic sedimentary successions belonging to the northern Gondwana margin and later to the Adriatic margin, a Neotethyan ophiolitic mélange and an uppermost Oligocene to Quaternary sedimentary cover (Figs. 2, 3; Šimunić et al., 1982; Aničić & Juriša, 1984).

Fig. 2
figure 2

Geological map of Ivanščica Mt. compiled from Šimunić et al. (1982) and the results of this study. The map shows the locations of cross-sections A-A’; B-B’ and CC’ (shown in Fig. 5) and sample locations used for apatite fission track dating. The location of the figure is shown in Fig. 1c. For colour coding of the tectonic features, please refer to Fig. 3. ČMT  Črne Mlake thrust, BZBT  Babin Zub back-thrust, GPF  Gotalovec-Prigorec fault

2.1 Lithostratigraphic characteristics of Paleozoic and Mesozoic rock units

The oldest rocks on Ivanščica Mt. are Permian brown–red conglomerates, sandstones and black shales conformably overlain by Lower Triassic clastic deposits, including sporadic1-2 m thick dolomite layer along the contact (Šimunić et al., 1982; Šimunić & Šimunić, 1997). Lower Triassic sediments consist of micaceous sandstone, mica siltstone, shale and marl in the lower part and dark-grey, tabular, thin-bedded limestone in the upper part (Šimunić & Šimunić, 1997). Paleozoic and Lower Triassic deposits have spatially limited exposure on the northern slopes of the mountain. These deposits originated from a shallow-marine environment (Šimunić et al., 1982).

The largest part of the mountain is built up of several hundred meters thick Middle Triassic deposits, predominantly shallow-marine dolomite and limestone (Fig. 2; Šimunić et al., 1982). Pelagic successions consisting of upper Anisian to Ladinian pelagic limestone and radiolarian chert are intercalated with basic to acidic volcanic and volcaniclastic lithologies (Goričan et al., 2005; Slovenec et al., 2020, 2023; Kukoč et al., 2023; Smirčić et al., 2024). These pelagic successions are several tens of meters thick, tectonically deformed and their contacts with the underlying and overlying formations are rarely exposed. Deep-marine basins formed during this period were relatively short-lived and carbonate platform sedimentation was reestablished in the Late Ladinian (Goričan et al., 2005). Upper Triassic sediments of Ivanščica Mt. are exclusively shallow-marine and consist of several hundred meters thick series of dolomite and limestone (Šimunić et al., 1982; Šimunić & Šimunić, 1997). These are the equivalent of the Hauptdolomit and Dachstein Limestone found in the Alps (Vukovski et al., 2023). Lower Jurassic to Lower Cretaceous deposits are exposed in the central part of Ivanščica Mt. The successions composed of these deposits differ in the southern and northern parts of central Ivanščica Mt. (Fig. 2). In the northern part, shallow-marine Lower Jurassic limestone conformably overlies Upper Triassic carbonates and is in turn overlain by Middle Jurassic pelagic limestone (Fig. 3; Vukovski et al., 2023). In contrast, in the southern part, Upper Triassic deposits are overlain by Lower Jurassic thick pelagic series consisting of pelagic limestone, carbonate breccia, marl and calcarenite (Fig. 3; Babić, 1974; Vukovski et al., 2023). Middle to Upper Jurassic radiolarian cherts are recorded in both areas, however, their contact with underling deposits and complete thickness is not known. In both areas, radiolarian cherts conformably pass up-section into Tithonian to Valanginian pelagic Aptychus limestone with several beds of calcarenites sporadically occurring at the contact as recorded in the southern part of central Ivanščica (Fig. 3; Babić & Zupanič, 1973; Vukovski et al., 2023). The youngest Mesozoic deposits are mixed carbonate-siliciclastic turbidites of the Hauterivian to Albian Oštrc Formation (Zupanič et al., 1981; Lužar-Oberiter et al., 2009, 2012), which overly the Aptychus limestone. On the southern slopes of Ivanščica Mt., in its central and eastern parts, an ophiolitic mélange is widely exposed, named as the Repno complex (Fig. 2; Babić & Zupanič, 1978; Babić et al., 2002). This ophiolitic mélange is composed of centimeter to hundred meters sized blocks of sandstone, chert, basalt and gabbro chaotically embedded within a shaly-silty matrix (Babić et al., 2002; Slovenec et al., 2011; Kukoč et al., 2024). The age of the blocks varies from late Anisian to late Oxfordian (Slovenec et al., 2011; Kukoč et al., 2024) while the ages derived from palynomorphs found in the matrix ranges from Hettangian to Bajocian (Babić et al., 2002).

Permian to Middle Triassic deposits were mostly deposited in the shallow-marine depositional environments along the northern Gondwana margin. Middle Triassic successions reflect a period of intense tectonic activity related to the continental rifting and break-up of Gondwana, which resulted in the opening of the Neotethys Ocean and formation of the Adriatic passive margin with horst-and-graben depositional environments (Goričan et al., 2005; Kukoč et al., 2023). Upper Triassic to Lower Cretaceous sedimentary successions of Ivanščica Mt. are interpreted as deposited on the eastern passive margin of the Adria microplate (Lužar-Oberiter et al., 2012; Vukovski et al., 2023), which was facing the evolving Neotethys Ocean from the Middle Triassic until the ophiolite obduction in latest Jurassic-earliest Cretaceous (Schmid et al., 2008, 2020). Sedimentation on the margin reflected regional tectonic activity. Resedimented shallow-marine material was likely supplied from the adjacent Adriatic Carbonate Platform (Vukovski et al., 2023). Hauterivian to Albian turbidites of the Oštrc Fm. have been interpreted as deposited in a clastic wedge in front of the advancing nappes carrying the Neotethys ophiolites (Lužar-Oberiter et al., 2009, 2012). The ophiolitic mélange is interpreted to have formed during the Middle Jurassic intra-oceanic subduction in the northern branch of the Neotethys Ocean (Western Vardar ophiolitic unit sensu Schmid et al., 2020) and subsequent Late Jurassic to earliest Cretaceous obduction of ophiolites of this oceanic realm on the eastern Adriatic margin (Babić et al., 2002; Kukoč et al., 2024).

2.2 Lithostratigraphic characteristics of Cenozoic rock units

The oldest Cenozoic deposits on Ivanščica Mt. comprise upper Egerian (lower Aquitanian) clastic deposits with coal seams (Fig. 3; Šimunić et al., 1982). On the southern slopes of the mountain, these deposits lay unconformably over different Mesozoic formations, locally also in tectonic contact with underlying Mesozoic formations (Fig. 2). On the northern slopes, upper Egerian (lower Aquitanian) clastic deposits are found in tectonic contact and steeply dip underneath the Mesozoic formations (Figs. 2, 5; Šimunić et al., 1982). In the neighboring area, only a few kilometers to the NW, complete Oligocene to Lower Miocene succession of dominantly marine clastic deposits have been described (Aničić & Juriša, 1984; Avanić et al., 2021). This around two kilometers thick Oligocene to Lower Miocene succession is interpreted as deposited within the so-called Hrvatsko Zagorje Basin (Fig. 3), a marginal basin of the Central Paratethys Sea (Avanić et al., 2021). The southern margin of the Hrvatsko Zagorje Basin is interpreted to be located along the present-day southern foothills of Ivanščica Mt. (Pavelić & Kovačić, 2018). Further to the south, the deposition of Cenozoic rocks commenced significantly later, in the Ottnangian (middle to late Burdigalian) or locally even Badenian (Langhian and early Serravallian; Pavelić & Kovačić, 2018). The deposition of Ottnangian to middle Badenian (middle to upper Burdigalian to upper Langhian) alluvial to marine succession with volcaniclastics marks the syn-rift period in the evolution of the newly formed so-called North Croatian Basin (Fig. 3; Pavelić, 2001; Pavelić & Kovačić, 2018). Further continuation of extension and accompanying transgression resulted in the unification of the Hrvatsko Zagorje and North Croatian basins during the early to middle Badenian (Langhian). Since then, both areas represent a single basin with a uniform lithostratigraphy (Fig. 3), occupying the south-western position in the Pannonian Basin (Pavelić & Kovačić, 2018). Middle Badenian (late Langhian) sediments are predominantly characterised by widespread sedimentation of marls and limestones (Pavelić & Kovačić, 2018). Regional late Badenian (early Serravallian) transgression and cessation of volcanic activity mark the end of the rifting stage and the onset of post-rift thermal subsidence (Pavelić & Kovačić, 2018). Sarmatian (late Serravallian) and early Pannonian (early Tortonian) sediments are characterized by marine to brackish marl and limestone. During the Late Miocene and Pliocene, the brackish lake was continuously in-filled by a turbiditic, deltaic, and finally alluvial clastic sequence (Pavelić & Kovačić, 2018), reflecting the diachronous regressive trend observed across the entire Pannonian Basin (Magyar et al., 2013). These were overlain by Quaternary clastic deposits (Šimunić et al., 1982).

Fig. 3
figure 3

Tectonostratigraphic columns showing detail lithostratigraphy of Middle Triassic to Lower Cretaceous successions of two structural domains and Cenozoic sedimentary cover. Note the difference in the Lower Jurassic deposits of ČMT footwall succession (IP structural domain) and ČMT hanging wall succession (IIF structural domain). Mesozoic lithostratigraphic columns are cut by faults of different ages and ČMT hanging wall succession is doubled in order to schematically show structural setting, ages and relations between different deformational structures as a result of different deformational events. Note the differences and similarities in Cenozoic deposits N of Šoštanj fault and those of Ivanščica Mountain

2.3 Structural characteristics

Structurally, Ivanščica Mt., together with other mountains in northern Croatia, is considered as the eastern part of an area locally known as the “Sava folds” (Fig. 1c; Šimunić et al., 1979, 1982; Šimunić 1992), a name characterizing a wedge-shaped tectonic domain in the Dinarides—Alps transition zone in eastern Slovenia and northern Croatia, with kilometer-sized E to ENE trending relatively open folds that deformed earlier formed tectonic units during Latest Cenozoic times (Winkler, 1923; Placer, 1999b). During their work on the Basic Geological Map of Yugoslavia, sheet Varaždin, Šimunić et al., (1979, 1982) considered all mapped faults on Ivanščica to be of Cenozoic age, the main contractional deformations occurring during the Miocene. These authors interpreted Ivanščica as a N verging nappe, which brought Paleozoic and Mesozoic formations over upper Oligocene and lowermost Miocene sediments during the Early Miocene (in Eggenburgian; late Aquitanian to early Burdigalian). The occurrences of Triassic-Jurassic carbonates in the southern part of central Ivanščica were interpreted as erosional remains of a structurally higher nappe (Šimunić et al., 1979, 1982) or as olistoliths embedded in the Repno complex (Babić & Zupanič, 1978). As we will show below, we newly interpret those occurrences as a stack of imbricates built up of Adriatic passive margin successions and the Repno complex that essentially formed during an Early Cretaceous contractional event.

More recent studies consider the northern Croatian mountains, including Ivanščica Mt., to be a part of the Southern Alps unit (Placer, 1999a). According to van Gelder et al. (2015) and Schmid et al., (2008, 2020) the continental units of Ivanščica Mt. are presently a part of the S verging South Alpine nappe emplaced over earlier formed Internal Dinaridic units during Miocene times. Prior to this south directed emplacement, the tectonic block carrying the northern Croatian mountains rotated 130° clockwise in Oligocene–earliest Miocene, as interpreted by Tomljenović et al. (2008). This interpretation is based on paleomagnetic data measured in Upper Cretaceous deposits on Medvednica Mt. The rotation resulted from earliest Miocene eastward lateral extrusion of the Alps and Dinaridic fragments, accompanied by strong dextral displacements along the Periadriatic fault system and Mid-Hungarian fault zone representing its eastern continuation (Fodor et al., 1998; Schmid et al., 2008). A prominent dextral strike-slip Šoštanj fault which tangent northern foothills of Ivanščica Mt. (Fig. 1c) represents the southernmost branch of the Periadriatic fault system (Fig. 1b; Vrabec & Foor, 2006; Atanackov et al., 2021). Subsequent normal faulting related to Early Miocene rifting and opening of this part of the Pannonian Basin overprinted older structures (Tomljenović & Csontos, 2001; van Gelder et al., 2015). Basin inversion, which was initiated in Late Miocene-Pliocene, caused folding and reverse faulting resulting in the final uplift of the north Croatian mountains (Tomljenović & Csontos, 2001). This inversion was synchronous with approximately 35° counterclockwise (CCW) rotation, active in Late Miocene to recent times, presumably driven by the CCW rotation and indentation of the Adriatic microplate (Tomljenović & Csontos, 2001; Márton et al., 2002).

3 Methods and results

3.1 Description of deformational structures

Ivanščica is a densely forested mountain with rather scarce high-quality geological outcrops. For this reason, extensive fieldwork was carried out. At locations considered as essential for better understanding of the deformational history of study area, detailed geological mapping at scales of 1:25,000 and 1:5000 was conducted. Special attention was given to the collection of structural and kinematic data, like orientation of bedding, meso-scale folds, axial planar cleavage, S-C fabrics, intersection lineations, fault planes and their kinematic indicators, many of these recorded for the first time in the area. Based on measured structural data, observed differences in deformation styles and mapped tectonic and depositional contacts shown in maps (Figs. 2, 4) and cross-sections (Fig. 5), the study area is subdivided into two structural domains that are from bottom to top: (1) Ivanščica Parautochthon (IP) and (2) Ivanščica Imbricate Fan (IIF). These are overlain by Cenozoic sedimentary cover (CSC) representing the post-tectonic sedimentary cover regarding the Mesozoic deformational events.

Fig. 4
figure 4

Simplified tectonic map of the Ivanščica Mt. showing spatial distribution of structural domains and Cenozoic sedimentary cover. ČMT  Črne Mlake thrust, BZBT  Babin Zub back-thrust, GPF  Gotalovec-Prigorec fault, PRF  Prigorec reverse fault

Fig. 5
figure 5

Cross-sections across Ivanščica Mt. Cross-sections A-A’ and B-B’ are perpendicular to the strike of structures in IIF and IP structural domains. Cross-section CC’ is longitudinal to the same structures. Positions of cross sections are shown in Fig. 2. For colour coding of the lithostratigraphic units, please refer to Fig. 2. ČMT  Črne Mlake thrust, GPF  Gotalovec-Prigorec fault, PRF  Prigorec reverse fault, ŠF  Šoštanj fault

3.1.1 Ivanščica Parautochthon (IP) structural domain

The Ivanščica Parautochthon (IP) structural domain comprises Permo-Mesozoic formations exposed along its northern slopes (Figs. 2, 5). As shown below, our new data do not suggest that IP structural domain would be of allochthonous nature nor do represent a part of a nappe. Therefore, we conclude that parautochthon is an appropriate term for this structurally lower domain. This domain is cut and broken apart into two structural blocks to the west and east of a prominent SE striking Gotalovec—Prigorec dextral strike-slip fault (GPF; see Fig. 2). In both structural blocks, IP structural domain is overthrust by the Ivanščica Imbricate Fan (IIF) structural domain along the SE dipping Črne Mlake roof thrust (ČMT; Figs. 2, 4 and 5). On its SW margin, the IP structural domain is unconformably overlain by upper Egerian (lower Aquitanian) and Miocene sediments. However, in part of the mountain SW of the Vilinska špica peak (726 m), Middle Triassic formations of the IP structural domain are brought over upper Egerian (lower Aquitanian) deposits by two NNW dipping reverse faults, with only locally preserved original depositional contact (Fig. 2). In contrast, no original depositional contacts between Cenozoic sedimentary cover and Permo-Mesozoic formations of the IP structural domain are preserved in the northern slopes of Ivanščica Mt. Here, Permo-Mesozoic formations of the IP structural domain are thrusted northward over upper Egerian (lower Aquitanian) sediments (Figs. 2, 5). In the central part of the mountain, the well preserved Permo-Mesozoic succession dips towards S to SE below the IIF structural domain and the upper Egerian (lower Aquitanian) to Miocene cover (Fig. 5). This homoclinal structure of the IP structural domain is thrusted towards NW over the rest of Permo-Mesozoic units belonging to the IP structural domain (Figs. 2, 5). These footwall units are arranged in several SE dipping imbricates and thrusted NW-ward over upper Egerian (lower Aquitanian) sediments at the northern margin of the mountain (Figs. 2, 5). The youngest strata found in this homocline are Hauterivian to Albian turbidites of the Oštrc Fm. They represent the highest footwall strata overthrust by Upper Triassic to Lower Cretaceous shallow- to deep-marine sedimentary succession in a hanging wall of the SE dipping ČMT (Figs. 4, 5). The Oštrc Fm. turbidites are characterized by meter- to meso-scale tight asymmetric folds with NE trending and dominantly SW dipping fold axes (Fig. 6a, b). In the same formation, this folding is associated with an axial planar cleavage (Fig. 6a, b). Moreover, in the underlying Aptychus limestone, similar but predominantly open asymmetric folds are documented showing the same NE trending orientation of fold axes as in the overlying turbidites. Overall consistency of fold asymmetries and SE dipping axial planes and axial planar cleavage (Fig. 6a, b) with respect to the stratification, indicate NW-ward direction of tectonic transport in present-day coordinates. This is in accordance with the tectonic transport direction observed for the structurally higher IIF structural domain (see below) and the overall kinematics of the ČMT.

Fig. 6
figure 6

Examples of kinematic data. a Stereoplot of the fold axes (L4) and intersection lineation (L4) of bedding (S0) – axial planar cleavage (S4), projected on top of the Kamb contour plot. Mean orientation of the fold axes is 231/20. The measurements are taken from pelagic Aptychus limestone and Oštrc Fm. exposed within the IP structural domain. b Tight asymmetric folding of siltstones and calcarenites of the Lower Cretaceous Oštrc Fm. exposed within the IP structural domain (46.172552, 16.058040). c Stereoplot of the poles to the bedding (S0), best fit Π-circle (shown with red line) and Π-axis. The measurements are taken from the Upper Triassic to lowermost Cretaceous deposits exposed within the IIF structural domain. d Slightly overturned NE dipping bedding (S0) and pervasive axial planar cleavage (S4) within siltstones and calcarenites of the Oštrc Fm. exposed within the IIF structural domain. Outcrop is located on the NW overturned limb of the syncline in the hanging wall of the BZBT (46.166424, 16.111421; see the cross-section B-B’ in Fig. 5) e NW dipping overturned bedding (S0) and pervasive axial planar cleavage (S4) within pelagic Aptychus limestone exposed in the IIF structural domain. Outcrop is located on the NW overturned limb of the syncline in the hanging wall of the BZBT (46.166978, 16.110589; see the cross-section B-B’ in Fig. 5). f Second-order S-type parasitic folding of Aptychus limestone exposed within the IIF structural domain (46.164857, 16.095013). g Stereoplot of the fold axes (L4) and intersection lineation (L4) of bedding (S0) – axial planar cleavage (S4), projected on top of the Kamb contour plot. Mean orientation of the fold axes is 251/9. The measurements are taken from the Jurassic to lowermost Cretaceous deposits exposed within the IIF structural domain. h Field photo of the SE dipping imbricate, NW dipping BZBT and Triangle structure in between. See Fig. 2 for the photo location

3.1.2 Ivanščica imbricate fan (IIF) structural domain

This structural domain occupies southern parts of central and eastern Ivanščica Mt. To the northwest, the domain thrusts over the IP structural domain along the SE dipping ČMT floor thrust (Figs. 2, 4 and 5). In the south, it is unconformably overlain by the upper Egerian (lower Aquitanian) and Miocene cover (Figs. 2, 4 and 5). The main structural characteristics of this domain are a series of SE dipping reverse faults splaying off the ČMT floor thrust (decollement), thus forming a stack of NW verging imbricates in their present-day orientation (Figs. 2, 5). These imbricates are made up of Upper Triassic platform carbonates, overlain by Lower Jurassic to Lower Cretaceous pelagic succession, dipping underneath the ophiolitic mélange of the Repno Complex. The latter was previously tectonically emplaced over the pelagic Jurassic to Lower Cretaceous succession (Figs. 2, 5). Thus, the formation of these imbricates postdates the emplacement of the ophiolitic mélange related to the obduction of the West Vardar ophiolites (Schmid et al., 2020). The lithostratigraphic composition of the imbricates changes towards NW in that the Repno complex thrusts over progressively younger formations starting with Lower Jurassic in the SE up to lowermost Cretaceous pelagic deposits in the NW (Figs. 2, 5). The Oštrc Fm. is present only in the NW-most imbricate, locally sandwiched between the ČMT and the antithetic reverse fault named the Babin Zub back-thrust (BZBT; Figs. 2, 4, 5). The formation of the BZBT was probably favoured by a steep ramp in the SE dipping ČMT (Fig. 5). The top SE transport along the BZBT is supported by the geometry of the overturned syncline with its parasitic folds and axial planar cleavage well developed in the pelagic Aptychus limestone and the Oštrc Fm. (Figs. 5, 6d-f). Thus, the BZBT and the first imbricate to the SE form a NE striking triangle structure (Figs. 2, 5 and 6h). Within the IIF, with the exception of the Repno complex, bedding planes and axial planar cleavage prevailingly dip towards SE (Figs. 5, 6c, g). In the overturned and tight syncline formed in the hanging wall of the BZBT bedding planes and axial planar cleavage dip to the NW (Figs. 5, 6c-e).

The outcrops of the Repno complex are characterized by pervasive scaly cleavage. The planar fabric is mainly represented by clay minerals. Shaly matrix incorporates variously sized blocks of basalt, gabbro, chert, and sandstone (Fig. 7b). Basalt and gabbro blocks are usually tens and up to hundred meters in diameter, while chert and sandstone blocks are centimetre up to tens of meters in diameter. Well-developed kinematic indicators (S-C fabrics, asymmetric and symmetric boudins) record inconsistent sense of shear (Fig. 7a–c). However, close to imbricate-bounding reverse faults, kinematic indicators in the Repno complex show a sense of shear consistent with the larger scale kinematics of these faults (i.e. top NW; Fig. 7c). In the southwestern part of the IIF, the structurally highest pre-Oligo-Neogene tectonic unit, the so-called Oštrc klippe thrusts over the Oštrc Fm. of the leading imbricate (Figs. 2, 5). This klippe comprises Upper Triassic platform carbonates and subordinately Jurassic pelagic deposits, both folded in a form of NE trending anticline (Figs. 2, 5).

Fig. 7
figure 7

Examples of kinematic data. a Stereoplot of the cleavage (S3) – cleavage (S4) intersection lineation (L4), projected on top of the Kamb contour plot. Mean orientation of the fold axes is 50–230. The measurements are taken from the ophiolitic mélange unit exposed within the IIF structural domain. Black poles represent intersection lineation derived from NW verging structures and red poles from SE verging structures. b Ophiolitic mélange exposed within the IIF structural domain (46.156851, 16.110643) embedding deformed symmetric blocks of sandstones in a shaly matrix. c S-C structures in the ophiolitic mélange exposed in the footwall just below the BZBT within the IIF structural domain (46.159118, 16.096405). d Stereoplot and associated paleostress tensor of strike-slip faults from the CSC. Measurements were taken along a generally ENE striking strike-slip faults to the north of Ivanščica Mt. e Strike-slip fault from the ENE striking dextral fault zone to the north of Ivanščica Mt. (46.219420, 16.192191), fault plane 140/82, striations 228/20, dextral displacement

3.1.3 Cenozoic sedimentary cover (CSC)

The Cenozoic sedimentary cover unconformably overlays the Permo-Mesozoic units and seals all the older structures of the structural domains described above. Thus, the Cenozoic sediments represent the post-tectonic cover of the previously described two structural domains. This can be observed on the southern slopes of Ivanščica Mt. where none of the NW verging reverse faults in the IIF structural domain extend into the upper Egerian (lower Aquitanian) sedimentary cover (Figs. 2, 5). Instead, the upper Egerian (lower Aquitanian) sediments gently dip towards S-SE and except for this gentle tilt do not show other deformational structures. In contrast, severe tectonic deformations affecting the Cenozoic deposits are observed along the northern margin of Ivanščica Mt. where upper Egerian (lower Aquitanian) sediments are overthrust by Permo-Mesozoic units of the IP structural domain along Prigorec reverse fault (PRF; Fig, 5). In addition to this, formations of the IP structural domain and the Cenozoic sedimentary cover are severely affected by transpressional faulting along a set of generally ENE striking dextral faults (Figs. 2, 5, and 7d, e). This fault set separates the Lepoglava syncline from the northwestern part of Ivanščica Mt. (see area of the left upper corner of Fig. 2) and is considered as an eastward prolongation of the dextral Šoštanj strike-slip fault (see Fig. 1c; Vrabec & Fodor, 2006; Atanackov et al., 2021). The youngest sediments clearly affected by this dextral fault set are of late Pannonian (late Messinian) age, but younger activity cannot be excluded. Another prominent structure is the SE striking Gotalovec – Prigorec dextral strike-slip fault (GPF in Figs. 2, 4) affecting uppermost Pannonian (Fig. 2) or possibly even younger deposits. South of Ivanščica Mt., similar dextral faults are not present or only have insignificant impact on the structural setting. Here folds and minor reverse faults of E-W to NE-SW orientation are most prominent structures (Figs. 2, 7).

3.1.4 Oligocene-Quaternary structures in the wider study area revealed by reflection seismic data

2D reflection seismic sections and well data are used to interpret and map structures in the subsurface in order to better understand the tectonic history of the study area. Traces of used seismic sections and positions of wells are shown in Fig. 1c. Pervasive polyphase deformation is registered across the whole study area, encompassing the entire Oligocene-Quaternary sedimentary sequence in which five characteristic types of structures were identified: extensional listric faults, inverted extensional listric faults, folds associated with reverse faults, positive flower structures, and reverse faults (Fig. 8).

Fig. 8
figure 8

Characteristic deformational structures interpreted on the seismic profiles

The Oligocene to Middle Miocene sedimentary sequences in the research area indicate the existence of two simultaneous and contrasting paleo-environments. Specifically, during this time interval, the area north of Ivanščica Mt. was characterised by the deposition of around two kilometres thick Oligocene to Lower Miocene dominantly marine deposits (Figs. 3, 9). These deposits are cut by the Šoštanj fault and except for the upper Egerian (lower Aquitanian) deposits, do not appear south of that dextral strike-slip fault. Upper Egerian (lower Aquitanian) deposits pinch-out to the south of Ivanščica Mt., where the oldest Cenozoic deposits are of Ottnangian (middle Burdigalian) or even late Badenian (early Serravallian) age.

Fig. 9
figure 9

a Regional composite cross-section composed of three segments. Segment 1–1’ is located to the north of Ivanščica Mt. Note the offset between section segment 1–1’ and B-B’. Segment B-B’ represents the homonymous cross-section from the Fig. 5. The legend for this section is shown in Fig. 2. Segment 2–2’ is located to the south of Ivanščica Mt. and ends at the easternmost slopes of Medvednica Mt. For exact location of the composite cross-section and its segments see Fig. 1c. b Lithostratigraphic columns of penetrated deposits from the wells Va-1 and HZ-1. For the locations of the wells see Fig. 1c. Note that the well Va-1 is not originally positioned but projected on the section segment 1–1’

The syn-rift structures are the oldest Neogene structures observed in the research area. According to reflector geometry and seismic facies characteristics, it is possible to differentiate Lower to Middle Miocene syn-rift units from older basement units (Fig. 9). Inside the basement, slightly inclined to horizontal echelon zones of sub-parallel, discontinuous, high amplitude reflectors are present (Figs. 8, 9), interpreted as listric normal faults that merge in depth into a detachment dipping towards the NE. Different generations of half-grabens developed in their hanging walls are observed on seismic sections. Based on well data, half-graben formation is constrained by thick syn-rift Lower to Middle Miocene deposits (Figs. 8, 9) penetrated by the Hz-1 well (Fig. 9, see also Tomljenović & Csontos, 2001). The post-rift deposits are of late Middle Miocene and/or early Late Miocene age (Figs. 8, 9). Notably, the absence of cross-cut features indicates a coherent deformation history during Early and Middle Miocene, however, in some cases with reactivation of earlier formed normal faults, and inversion of extensional listric faults into reverse faults (Fig. 8). This tectonic inversion is coeval with Sarmatian (late Serravallian) to earliest Pannonian (early Tortonian) deposition.

Three groups of structures are observed in the deformed post-rift Upper Miocene and Pliocene deposits. The first are reverse faults with SE and NW vergence, predominantly in the area between Ivanščica and Medvednica Mt. (Figs. 8, 9). Displacement on these faults is commonly up to hundreds of meters. As a result, the basement units are brought above Upper Miocene deposits in their footwalls. Between the Ivanščica Mt. and the Hz-1 well (Figs. 2, 9), a general vergence of these faults is towards SE, while in between this well and Medvednica Mt. reverse faults mostly dip towards SE and have NW vergence (Fig. 9). These reverse faults are usually formed as conjugate faults, and commonly bound the E-W to NE-SW striking, open and symmetric anticlines or pop-ups in their hanging walls. The most prominent structure between Ivanščica and Medvednica mountains is the Konjščina syncline (Fig. 9). In the core of this syncline 2000 m of Upper Miocene, Pliocene, and Quaternary deposits were penetrated by the Hz-1 well (Fig. 9). Onlap and downlap reflection terminations are common, but mainly connected to the syn-depositional clinoform architecture related to the basin-scale morphological shelf progradation (Fig. 9). However, the onlap features observed above the Upper Miocene clinoform unit around Hz-1 well, are folded together with the prominent reflector on which they onlap (Fig. 9). Considering the data from the Hz-1 well, this unit is represented by an alternation of sandstone and marls, which are unconformably overlain by Plio-Quaternary gravels at depth of 580 m (Fig. 9). This unconformity surface is folded and pinches out towards Strugača anticline to the N and eastern Medvednica Mt. to the S. As observed on seismic and surface structural data, the overlying Plio-Quaternary deposits are also folded and faulted (Fig. 9). The next prominent syncline is the SE trending Lepoglava syncline located to the N of Ivanščica Mt. between two regional dextral faults, the Šoštanj fault to the S and Donat fault to the N (Figs. 1, 2).

3.2 Apatite fission track

Apatite fission track (AFT) analyses were carried out by the Institute of Geology at Czech Academy of Sciences. Samples for AFT analysis were collected from both Permo-Mesozoic structural domains to compare their thermal histories and reconstruct the uplift path of the Alpine—Dinaridic transitional zone. Since the study area consists mostly of carbonate sedimentary rocks and thus lacking apatite-rich lithologies, we selected the only three potentially suitable lithostratigraphic units for apatite extraction. Among overall eight samples collected from Permian to Lower Triassic sandstones, Middle Triassic volcanic rocks and Lower Cretaceous turbidites, only three samples from Permian to Lower Triassic sandstones gave enough apatites for analysis and only two of them (GV-1609 and GV-1625; Fig. 2) were successfully analysed Table 1. The apatite extraction from the rock samples (8 kg per sample) was done following standard mineral separation (REF) and their preparation for counting and subsequent measurement of uranium content by using LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) following the procedure and age calculation described by Hasebe et al. (2004). IsoplotR software (Vermeesch, 2018) and Durango apatite standard were used for zeta factor calculation and final calculation of ages.

Table 1 Apatite fission track analytical data

The results of two AFT analyses are presented in Table 1. Two analysed detrital samples from the IP structural domain yield a central age of 56.36 ± 2.50 Ma for GV-1609 and 67.27 ± 5.38 Ma for GV-1625 (Fig. 10). Measured mean track length is 11.12 ± 2.54 μm for the sample GV-1609 and 11.76 ± 1.76 μm for the sample GV-1625. The AFT age and length measurements were combined with paleo temperature and stratigraphic constraints in order to derive the cooling trajectories for both samples by using HeFTy software based on fission track annealing algorithms (Ketcham, 2005; Ketcham et al., 2007). The obtained time–temperature model of both samples (Fig. 10) indicates fast, tectonically induced cooling that took place immediately after peak temperature conditions reached in the Early Cretaceous (ca. 140 Ma). The model suggests a drop of a temperature from a minimum 300 to 100 °C between 140 and 125 Ma and a minimum cooling rate of 13.33 °C/Ma. This implies denudation rate of 0.53 km/Ma when assuming an average thermal gradient of 25 °C/km. The length of the apatite fission tracks corrected for the angle of measurement indicates a subsequent and relatively slow cooling period through the apatite partial annealing zone (APAZ) followed by a stable period with only minor fluctuations around the lower temperature limit of the APAZ (Fig. 10).

Fig. 10
figure 10

Apatite fission track data. Radial plots (plots to the left) showing the distribution of cooling ages according to the relative error and standard deviation for the apatites, accompanied by a graphs showing the distribution of the track lengths in the apatites (graphs in the middle) and a t/T graphs (graphs to the right) showing the results of HeFTy modeling based on track length and age distribution of the apatite fission tracks. n  number of used data, MSWD  mean square of weighted deviates, P(χ2) = probability of obtaining chi-square (χ2) for n degrees of freedom (n is the number of crystals; APAZ  apatite partial annealing zone

3.3 Vitrinite reflectance

Vitrinite reflectance (VR, %Ro) was measured on isolated organic matter using Zeiss Axio Imager microscope equipped with MSP 210 microscope spectrometer (oil immersion) following standard procedures (Stach et al., 1982; Taylor et al., 1998). First, total organic carbon (TOC) content was determined on selected samples (siltstones and mudstones of Cretaceous, Jurassic, and Triassic age). The TOC content was measured on Leco C744 carbon analyser. To remove carbonate material, samples were pre-treated with hot 18% HCl. Then, organic matter (kerogen) was isolated. Organic matter concentrate was obtained after standard HCl/HF/ZnCl2 treatment of rock. Standards used for calibration were Spinel (0.426%Ro), Sapphire (0.596%Ro), Yttrium–Aluminium-Garnet (0.905%Ro), Gadolinium-Gallium-Garnet (1.721%Ro), Cubic-Zirconia (3.12%Ro), Strontium-Titanate (5.38%Ro). VR was converted to peak paleotemperatures using formulas defined by Barker & Pawlewicz (1994) for burial heating (Tpeak = (lnRr + 1.68)/0.0124). Organic matter was examined on Olympus BX-51 microscope.

The organic matter content in the analysed siltstones and mudstones ranges from 0.16 to 1.16 wt% TOC (Table 2). Generally, organic matter content is low (TOC < 0.3%) except in Jurassic (GV-476) and Triassic (GT-240) siltstones (0.91 and 1.16% TOC, respectively). Organic matter is mainly fine detrital and of terrigenous origin, represented either with vitrinite macerals or with dark, non-fluorescent, highly thermally altered amorphous organic matter. Inertinite, mainly fusinite particles are evidenced as well.

Table 2 Vitrinite reflectance analytical data

Middle Triassic organic matter is highly thermally altered. VR (3.84%Ro) corresponds to paleo-temperatures of ≥ 245 ºC (Bostick, 1979; Barker & Pawlewicz, 1994; Rainer et al., 2016). Organic matter in Lower Jurassic mudstones is mainly amorphous while in Jurassic siltstones vitrinite macerals prevailed. VR and TAI (thermal alteration index) in all Jurassic samples indicate transition from catagenesis into metagenesis except in GV-1477 sample. VR in GV-1477 is higher (2.93%Ro) than in two others measured (1.86 and 1.95 respectively) pointing to higher paleotemperatures (> 225 ºC) in that sample in relation to other ones (≈ 190 ºC). According to VR and TAI Lower Cretaceous siltstones have reached onset of metagenesis. VR is slightly higher than 2%Ro indicating paleotemperatures ≥ 200 ºC.

4 Discussion

4.1 Tectonic evolution of the study area and correlation with the Dinarides and the Alps

Integration of structural, AFT and VR data, together with the existing sedimentological and biostratigraphic data, enabled a reconstruction of the five deformational events that affected Permo-Mesozoic and/or Cenozoic formations of Ivanščica Mt. In addition, based on lithostratigraphic characteristics of volcano-sedimentary successions and their superposition, two older Mesozoic extensional events are also supposed. These events are discussed below in the context of the tectonic evolution of Ivanščica Mt. and in the context of the tectonic evolution of the Dinarides, Southern and Eastern Alps. The chronology of deformational events was partly derived from overprinting relations between documented deformational structures and partly based on new biostratigraphic ages of Mesozoic successions (Vukovski et al., 2023) considered as pre-, syn- and post-tectonic deposits with respect to particular deformational events. Additional time constraints were established based on AFT data.

4.1.1 Pre-Cretaceous tectonic evolution

The oldest deformational event (D1 extension) on Ivanščica Mt., although not directly confirmed by deformational structures, is indicated by the presence of syn-rift volcano-sedimentary successions of Middle Triassic age. Anisian to Ladinian pelagic successions documented in the IP structural domain (Figs. 2, 3), are interpreted as having been deposited in relatively deep depocenters arranged in the form of half-grabens controlled by steep normal faults (Goričan et al., 2005; Slovenec et al., 2020, 2023; Kukoč et al., 2023). On Ivanščica Mt., the oldest pelagic deposits are Illyrian (late Anisian) radiolarian cherts (Goričan et al., 2005; Slovenec et al., 2020; Kukoč et al., 2023), while on nearby Kuna gora Mt. ammonites from pelagic limestones indicate a Pelsonian (middle Anisian) age (Kukoč et al., 2023). Thus, according to our interpretation, this oldest deformation (D1) represents an extensional event that is related with the opening of the Neotethys Ocean during Middle Triassic times. These half-graben depocenters were short-lived, and a shallow-marine carbonate sedimentation was re-established again in the Late Ladinian (Šimunić & Šimunić, 1997; Goričan et al., 2005). Such an Anisian-Ladinian extensional event is well-documented throughout the Alps and the Dinarides, characterized by deposition of coeval and lithologically similar volcano-sedimentary successions (for correlation, see Kukoč et al., 2023).

During the Early Jurassic, after a period of Late Triassic shallow-marine sedimentation proved by Upper Triassic carbonates found in both pre-Miocene structural domains of Ivanščica Mt. (i.e., in IP and IIF structural domains), a dramatic change in depositional environments took place. In the IP structural domain, deposition of shallow-marine carbonates continued from Late Triassic into Early Jurassic until the Pliensbachian. In contrast, in the IIF structural domain the Upper Triassic shallow-marine carbonates are covered by Lower Jurassic pelagic deposits. This sharp deepening of depositional environments is assumed as related to yet another extensional event of Early Jurassic age (D2). As IP and IIF structural domains are separated by the ČMT (Figs. 2, 4 and 5), this NW verging thrust (recent orientation) is likely an inverted Early Jurassic normal fault. However, since Pliensbachian, pelagic conditions prevailed in both structural domains (Vukovski et al., 2023). This Early Jurassic extensional event correlates well with Jurassic rifting recorded in the Dinarides (Blanchet et al., 1970; Babić, 1976; Dragičević & Velić, 2002) and in the Southern and Eastern Alps, where similar lithostratigraphic successions are documented (e.g. Bertotti et al., 1993; Bohm, 2003; Goričan et. al 2012; Rožič et al., 2017). In the Alps, this Early Jurassic extension led to formation of the Alpine Tethys passive continental margin (e.g., Froitzheim & Eberli, 1990; Froitzheim & Manatschal, 1996).

4.1.2 Early Cretaceous tectonic evolution

The tectonic emplacement of the Repno Complex over the stratigraphic succession of the Adriatic continental passive margin recorded in the IIF structural domain (Figs. 2, 5, 11) marks the oldest contractional event recorded on Ivanščica Mt. (D3). Age constraints for this event on Ivanščica Mt. are provided by the youngest formations that are directly overthrust by the Repno Complex, which is uppermost Tithonian to Valanginian Aptychus limestone (Fig. 5). This indicates that the D3 event occurred during the Valanginian or slightly earlier.

Fig. 11
figure 11

Schematic geodynamic reconstruction of the wider study area (northwesternmost Internal Dinarides) during Early Cretaceous. Different symbology is used for the faults to represent different stages in their activity as explained in the legend. Orange coloured faults were formed during D3 event related to the obduction of ophiolites and ophiolitic mélange. D3 obduction caused metamorphism in the distal domains of the Adriatic passive margin (e.g. Medvednica Mt.), while proximal domains experienced thermal overprint. Red coloured faults were formed in subsequent D4 event and are responsible for the exhumation of Adriatic passive margin successions together with overlaying ophiolitic mélange, which enable their erosion and resedimentation within turbidites of the Oštrc Fm

The peak temperature conditions of approximately 200 °C recorded in the passive margin successions within the IIF structural domain (Table 2) were likely reached during this event. The obtained temperatures, calculated using the vitrinite reflection method, are only slightly higher than those estimated from the colour of pollen and dinoflagellate cysts obtained from the Repno Complex (Babić et al., 2002). This is in line with the structurally higher position of the Repno Complex with respect to the underlying passive margin successions.

Late Jurassic to earliest Cretaceous obduction of the Neotethyan ophiolites on the eastern continental margin of Adria is well documented throughout the Dinarides and the Hellenides (e.g., Bortolotti et al., 2013; Tremblay et al., 2015; Nirta et al., 2018; Schmid et al., 2020 with references). It is proposed that this obduction is responsible for a low-grade metamorphic overprint recorded in Paleo-Mesozoic units of the distal Adriatic margin underlying the ophiolites (see Fig. 11; e.g., Tomljenović et al., 2008; Porkoláb et al., 2019; Mišur et al., 2023). On Medvednica Mt., monazite dating indicates a Berriasian metamorphic event (~ 143 Ma; Mišur et al., 2023), while in the central Dinarides, K/Ar ages indicate Tithonian to Valanginian age of this metamorphic overprint (150–135 Ma; Porkoláb et al., 2019). Therefore, Valanginian age assumed for the D3 deformational event on Ivanščica Mt. is only slightly younger than these metamorphic ages. However, as Permian to Lower Cretaceous formations of Ivanščica Mt. are not affected by this metamorphic overprint but only a minor thermal overprint, at the time of the obduction they were in a more external (i.e., continent-ward) paleogeographic position on the Adriatic margin than units affected by this metamorphism (Fig. 11). In the central Dinarides, the youngest deposits directly overthrust by the Neotethyan ophiolites and ophiolitic mélange have so far been described from the East Bosnian-Durmitor thrust sheet where the ophiolitic mélange is found in a tectonic position above Tithonian to Berriasian pelagic limestone (Vishnevskaya et al., 2009). This limestone is correlative to the Aptychus Limestone from Ivanščica, although its age is constrained within a shorter stratigraphic range. Middle Triassic to Lower Cretaceous succession exposed on Ivanščica Mt. and attributed to the Adriatic continental margin correlate well with contemporaneous successions described from the Pre-Karst unit of the central Dinarides (Vukovski et al., 2023 with references).

Population of detrital zircons from the Oštrc Fm. with an Early Cretaceous cooling ages (ca. 145 − 134 Ma; Lužar-Oberiter et al., 2012) was sourced from these more internal units (e.g. Medvednica Mt.), where zircons were reset due to obduction (D3) and exhumed during subsequent D4 event.

The second contractional event recorded by deformational structures documented in the IIF and IP structural domains of Ivanščica Mt. is the D4 event. It resulted in the formation of contractional structures observed at different scales. These include NW verging imbricates of the IIF structural domain, which comprise the Repno complex and its tectonic footwall consisting of the Upper Triassic and Jurassic Adriatic passive margin succession (Figs. 5, 11). NW-ward directed thrusting of the IIF structural domain over the IP structural domain along the ČMT (Fig. 5), the formation of the BZBT (Figs. 5, 6h), NW-ward reverse faulting in the IP structural domain (Fig. 2) and intense pervasive folding of non-competent Jurassic to Lower Cretaceous pelagic deposits within both structural domains are also attributed to this deformational event (Fig. 6a–f). Sedimentological evidence supports a late Early Cretaceous age of this contractional event. The youngest deposits affected by this event are turbidites of the Hauterivian to Albian Oštrc Fm., thus indicating that this event should be at least partly post Albian in age. However, as the Oštrc Fm. contains lithoclasts of the underlying uppermost Tithonian to Valanginian Aptychus limestone (Zupanič et al., 1981), we consider this formation as syn-tectonic with respect to D4 deformational event. In addition to lithoclasts of the Aptychus limestone, the Oštrc Fm. contains other shallow-marine to pelagic lithoclasts of Triassic-Jurassic age, as well as mafic volcanic lithoclasts and abundant Cr-spinel grains (Zupanič et al., 1981). The source of all these lithoclasts and Cr-spinels is seen in the imbricates of the IIF (Figs. 5, 11). This indicates a strong, tectonically induced, fast syn-sedimentary Hauterivian to Albian exhumation and erosion of the uppermost Triassic to lowermost Cretaceous Adria passive margin succession together with the tectonically overlaying Repno complex (Fig. 11). This is in agreement with our AFT time–temperature models (Fig. 10) suggesting fast tectonically induced Early Cretaceous cooling and exhumation. The upper age limit of D4 event cannot be precisely constrained on Ivanščica Mt. due to the lack of post-tectonic cover deposits older than upper Egerian (lower Aquitanian). However, on the neighbouring Medvednica Mt. a correlative deformational event, D1 of van Gelder et al. (2015) or D2 of Tomljenović et al. (2008), predates the Late Cretaceous transgression and deposition of the Gosau-type sediments (Glog Fm.; Lužar-Oberiter et al., 2012 with references). Considering an Oligocene-earliest Miocene ca. 130° clockwise rotation of the block carrying Medvednica and neighbouring northern Croatian mountains (including Ivanščica) proposed by Tomljenović et al. (2008), the original trend of the D4 deformational structures documented on Ivanščica would be NW–SE and with top SW direction of tectonic transport. In that case, the initial pre-Miocene orientation and vergence of the D4 structures on Ivanščica Mt. would correspond well with contemporaneous and commonly observed SW verging structures in the Internal Dinarides (Dimitrijević, 1997; Tari, 2002; Schmid et al., 2008; Schefer, 2010; Porkoláb et al., 2019, Nirta et al., 2020).

The thermal overprint recorded in Mesozoic sediments of the IP structural domain likely reflect the D4 deformational event, since unlike the IIF structural domain, the IP was not overthrust by an ophiolitic mélange unit. Instead, continuous sedimentation of the Oštrc Fm. on top of the Aptychus limestone is recorded in the IP structural domain (Figs. 2, 5). Therefore, we propose that peak temperature conditions in the IP structural domain were reached during D4 thrusting of the IIF structural domain over the IP, soon followed by the exhumation and cooling due to propagation of this thrusting towards the Adriatic foreland. In-sequence D4 thrusting is supported by the presence of the syn-tectonic Oštrc Fm. exclusively found in the leading sector of the IIF (Figs. 2, 5 and 11). Conodont fragments from Middle Triassic limestone exhibit CAI (conodont alteration index) value of 5–6 (Kukoč et al., 2023) corresponding to a minimum temperature of 300 °C which is slightly higher but still comparable with our VR results.

In the central Internal Dinarides, contractional deformational event correlative with the D4 documented on Ivanščica postdates the ophiolite obduction and predates the deposition of Upper Cretaceous ‘overstepping’ sequences (see in Nirta et al., 2020). Here, this event is manifested in SW-ward nappe stacking, exhumation, erosion and re-deposition of passive margin units of the distal Adriatic margin together with overlaying ophiolitic units (Schmid et al., 2008; Schefer 2010; Tremblay et al., 2015; Porkolab et al., 2019; Nirta et al., 2020), also affecting the syn-orogenic turbiditic Vranduk Fm. and its proximal equivalent the Pogari Fm. (Mikes et al., 2008; Nirta et al., 2020). These formations are correlative with syn-orogenic Hauterivian to Albian Oštrc Fm. and Aptian–Albian shallow-water Bistra Fm. (Gušić, 1975; Crnjaković, 1989; Lužar-Oberiter et al., 2012) unconformably overlying the Repno Complex in Medvednica Mt. Still, Oštrc and Bistra formations are younger than the Vranduk and Pogari formations (Mikes et al., 2008; Nirta et al., 2020 with references therein; Hrvatović, 2022), thus suggesting younger age of D4 deformations and more forelandward position of Ivanščica Mt. during this event.

In the Eastern Alps, Early Cretaceous contractional deformational event correlative with the D4 event of Ivanščica is well-known as the Eo-Alpine event characterized by WNW-ward stacking of the Austroalpine nappe units (Fig. 12; Neubauer et al., 1999; Schmid et al., 2008, 2020 and references therein) and a deposition of the syn-orogenic Rossfeld Formation of late Valanginian to Aptian age (~ 135 − 110 Ma; Faupl & Wagreich, 2000). Moreover, a regional Early Cretaceous event is documented along the whole East Alpine-Dinaridic-Hellenic belt (Neubauer et al., 1999; Schefer, 2010; Bortolotti et al., 2013), including the Western Carpathians (Plašienka et al., 1997a, b). In general, it is interpreted as related to the closure of the northern branch of the Neotethys Ocean (Fig. 12; Schmid et al., 2008; 2020; Nirta et al., 2018, 2020).

Fig. 12
figure 12

An overview and correlation of the most important tectonic events documented on Ivanščica Mt. (Kukoč et al., 2023, Slovenec et al., 2023; Vukovski et al., 2023 and the results of this study), in the eastern Southern Alps (Doglioni & Bosellini, 1987; Castellarin et al., 1992; Doglioni, 1992; Sarti et al., 1992; Bertotti et al., 1993; Channell, 1996; Schönborn, 1999; Mandl, 2000), the Eastern Alps (Kozur, 1991; Ratschbacher et al., 1991; Schmid et al., 1996; Dunkl & Demény, 1997; Froitzheim et al., 1997; Neubauer et al., 1999; Willingshofer et al., 1999a, b; Faupl and Wagreich, 2000; Mandl, 2000; Böhm, 2003; Thöni, 2006; Gawlick et al., 2009; Missoni & Gawlick, 2011a, b; Favaro et al., 2015; Rosenberg et al., 2015; Gawlick & Missoni, 2019; Fodor et al., 2021), Dinarides (Gušić & Babić, 1970; Lanphere et al., 1975; Dragičević & Velić, 2002; Lugović et al., 2006; Schmid et al., 2008; Ustaszewski et al., 2009; Smirčić et al., 2018, 2020; Porkolab et al., 2019; van Unen et al., 2019a, b; Nirta et al., 2020; Šegvić et al., 2020; Balling et al., 2023; Slovenec & Šegvić, 2024), Pannonian Basin (Tomljenović, 2002; Tomljenović & Csontos, 2001; Horváth et al., 2006; Balázs et al., 2016) and nearby Medvednica Mt. (Tomljenović et al., 2008; van Gelder et al., 2015; Mišur et al., 2023). Note how the tectonic events are linked with the geodynamic processes within the Neotethys Ocean (Channell & Kozur, 1997; Stampfli & Borel, 2002; 2004, Schmid et al., 2004). Time scale after Cohen et al., (2013; updated). DLS  Dinaride Lake System, SSZ  supra subduction zone

The D4 event resulted in a regional emersion recorded on Ivanščica Mt. as well as throughout the Dinarides and the Eastern Alps. The oldest sediments covering Mesozoic formations on Ivanščica Mt. are upper Egerian (lower Aquitanian) clastic deposits (Fig. 2). Locally across the Dinarides, this emersion was considerably shorter and lasted until the Late Cretaceous when ‘overstepping sediments’ were deposited on top of Mesozoic formations (Nirta et al., 2020; Hrvatović, 2022). Similarly, in the Medvednica Mt. these sediments are known as Gosau-type deposits and are of Santonian to Paleocene age (Crnjaković, 1979). Additionally, lateritic sediments on top of serpentinites are found at the base of a Campanian rudist limestone (Palinkaš et al., 2006; Moro et al., 2010). Another evidence of emersion can be found in bauxite deposits on the neighbouring Ravna gora Mt. formed on top of Triassic dolomites, likely exhumed during the D4 event. Bauxites are sealed by upper Eocene Foraminiferal limestone (Šimunić et al., 1981; Šimunić, 1992; Ćosović & Drobne, 2000). Post Early Cretaceous emersion in the study area suggests that Late Cretaceous to Eocene sedimentary burial cannot be the explanation for the thermal overprint, as it is interpreted for the area of “Sava folds” and further westward in Slovenian Basin where continuous latest Cretaceous to middle Eocene sedimentation resulted in deposition of at least 5 km of flysch type sediments (Rainer et al., 2016). Records of this emersion, which lasted from latest Jurassic to earliest Cretaceous until the Late Turonian transgression and the deposition of the Lower Gosau Group are found in the Austroalpine unit and the Western Carpathians (Wagreich & Faupl, 1994; Wagreich & Marschalko, 1995; Stern & Wagreich; 2013; Steiner et al., 2021).

The cooling trajectories of the AFT samples obtained in this study indicate a tectonically stable period with only minor fluctuations after the fast cooling related to the D4 event (Fig. 10). The central ages of 56.4 ± 2.5 Ma for sample GV-1609 and 67.3 ± 5.4 Ma for sample GV-1625 are the result of a long-lasting period during which these samples remained around the lower limit of the APAZ (Fig. 10). For this reason, we suppose that the IP and the IIF structural domains were not affected by any major deformation postdating D4 Early Cretaceous contraction and predating D5 Early Miocene extension.

4.1.3 Neogene-recent tectonic evolution

NE dipping low angle listric normal growth faults documented on reflection seismic sections (Fig. 8), associated with ENE striking dextral strike-slip faults around the prominent Early Miocene syn-rift depocenters N of Ivanščica Mt. (Figs. 1c, 2) are attributed to the D5 deformational event that resulted in Early Miocene NE-SW directed extension. The D5 normal faults crosscut older structures (Fig. 5) with only sporadic evidence for their later inversion or reactivation. The termination of D5 extension is marked by the late Badenian (early Serravallian) transgression and deposition of clastic to carbonate sediments, which seal Early Miocene rift structures (Figs. 8, 9). The termination of this event corresponds with a gradual decrease in volcanic activity during late Middle Miocene in the Pannonian Basin (Balázs et al., 2016; Pavelić & Kovačić, 2018). Onlapping of Pannonian (Tortonian to lower Zanclean) over Sarmatian (upper Serravallian) sediments indicates a late Sarmatian (latest Serravallian) short-lived contraction (D6), also documented in reflection seismic sections near Medvednica Mt. by Tomljenović & Csontos (2001). It resulted in partial reactivation of the D5 normal listric faults into reverse faults (Fig. 8). The subsequent stage of thermal subsidence well documented across the entire Pannonian Basin area was characterised by filling of accommodation space and gradual filling of the basin during Late Miocene and Pliocene times (Kovačić et al., 2004; Sebe et al., 2020).

The youngest deformation event (D7) is of Late Miocene to recent age, and characterized by NNW-SSE contraction. To the north of Ivanščica Mt., this contraction is accommodated by the reactivation of ENE striking dextral faults (e.g. Šoštanj fault; Fig. 7d, e) and by formation of E to ENE trending km large folds and SE striking dextral faults (Fig. 2). Here, reverse faulting is mostly accommodated along local transpressional ramps of major strike-slip faults. The influence of strike-slip faulting decreases sharply to the south at the N to NW verging Prigorec reverse fault (Figs. 2, 5), which possibly represents Early Cretaceous D4 fault reactivated during D7 Late Miocene-Present contraction. This fault is responsible for NW-ward high angle thrusting of the Permo–Mesozoic units of the IP and passively transported IIF over upper Oligocene and Miocene deposits, inclination of homoclinal S to SE dipping Miocene strata in the southern slopes of the mountain (Fig. 5), and final uplift of Ivanščica. The SE striking Gotalovec – Prigorec dextral fault is attributed to the D7 event according to the late Pannonian (late Messinian) age of deformed strata. To the south and towards the Medvednica Mt., the same NNW-SSE contraction resulted in the formation of series of E to ENE trending, tens of kilometres long anticlines and synclines, with small offset reverse faults developed in the limbs of anticlines (Figs. 8, 9). Onlapping and thinning of syn-tectonic strata along the flanks of anticlines indicate that the main stage of folding started in the late Pannonian (late Messinian; Figs. 8, 9). This deformation and timing correlates well with previous field kinematic studies and interpretations of seismic data from wider study area (Placer, 1999b; Tomljenović & Csontos, 2001; van Gelder et al., 2015; Balázs et al., 2016).

4.2 Tectonic position of Ivanščica Mt.

Earlier studies considered Ivanščica, for the most part, as a S verging Neogene nappe of the South Alpine unit, thrusted over the ophiolitic mélange of the Western Vardar ophiolitic unit of the Dinarides (Repno complex; Fig. 1c; Placer, 1999a; Schmid et al., 2008, 2020; van Gelder et al., 2015). Our investigation did not reveal any S to SE verging thrust of Miocene age. The only SE verging fault is the BZBT, the location and kinematics of which partially coincides with the frontal thrust of the South Alpine unit according to Placer, (1999a), van Gelder et al. (2015) and Schmid et al. (2020). However, the BZBT is sealed by upper Egerian (lower Aquitanian) deposits and thus predates Oligocene–earliest Miocene rotation. Furthermore, we interpret the BZBT to be Early Cretaceous in age (see Sect. 4.1.2.). Therefore, the initial top-NE vergence of the BZBT and its Early Cretaceous age oppose the interpretation about SE-ward Miocene thrust. In addition, the main shortening phase in the South Alpine unit (the Valsugana phase, ca. 14–8 Ma, Castellarin et al., 1992; Doglioni, 1992; Castellarin & Canteli, 2000; Zattin et al., 2003, 2006), was coeval with the regional transgression and the deposition of shallow-water to pelagic sediments in the study area (Fig. 12), including whole Pannonian Basin (Balázs et al., 2016; Pavelić & Kovačić, 2018 and references therein). However, the same driving process which caused thrusting within the South Alpine unit, the indentation and CCW rotation of Adria, is responsible for the late Pannonian (late Messinian; ~ 6 Ma) to recent contraction (D7). In the area of the Dinarides and the Pannonian Basin, this contraction resulted in folding, reverse and strike-slip faulting (Tomljenović & Csontos, 2001; Balázs et al., 2016; van Unen et al., 2019a, b). In contrast, at the same time the South Alpine unit was characterised by thrusting (Castellarin et al., 1992; Picotti et al., 2022). Hence, in contrast to the previous studies, our data suggest that the study area was not affected by the Miocene S-ward retro wedge thrusting characteristic for the South Alpine unit. Instead of S-ward thrusting, in the study area indentation of Adria was manifested by folding, reverse and strike-slip faulting. Considering the Mesozoic tectono-sedimentary evolution of Ivanščica Mt. (Figs. 3, 12) as described earlier in the discussion, we interpret paleogeographic affiliation of its non-ophiolitic Mesozoic structural-stratigraphic entities to the Pre-Karst unit of the Dinarides. The Repno complex belongs to the Western Vardar ophiolitic unit representing its northwesternmost outcrops. Up to now, this is the only known location where ophiolitic mélange of the Western Vardar ophiolitic unit is in the primary obduction thrust contact with underlying successions of the Pre-Karst unit (Figs. 5, 11).

5 Conclusion

Ivanščica Mt., an inselberg in the Alpine—Dinaridic transitional zone of northern Croatia, is divided into two structural domains: Ivanščica Parautochthon and Ivanščica Imbricate Fan overlain by Cenozoic sedimentary cover.

By implementation of a multi-scale structural analysis, AFT, and VR data, four contractional and one extensional event have been recorded on Ivanščica Mt. In addition, two older extensional events were recognized based on the Mesozoic tectono-sedimentary record. Middle Triassic (D1) and Early Jurassic (D2) extensional events related to the opening of the Neotethys Ocean and Alpine Tethys respectively are recorded in volcano-sedimentary successions of the IP and the IIF structural domains.

Late Berriasian to Valanginian (~ 140 Ma) contraction (D3) is manifested with tectonic emplacement of the ophiolitic mélange of the Repno Complex over the stratigraphic successions of the Adriatic passive margin in the IIF structural domain and their thermal overprint.

The following contractional event (D4) was a NW-ward imbrication, thrusting of the IIF structural domain over the IP structural domain along the ČMT and thermal overprint of sedimentary succession of the IP. Syn-deformational Hauterivian to Albian Oštrc Fm. and our AFT modelling results provide age constraints for this deformational event (~ 133–100 Ma). When considering the post Oligo-Miocene rotations, initial NW trending and SW verging structures attributed to D4 deformational event coincide with the typical Dinaridic structural trend. This deformational event is a result of continued contraction related to the closure of the northern branch of the Neotethys Ocean and finally resulted in long lasting emersion in the Ivanščica Mt.

The youngest extensional event (D5) is characterized by formation of NE dipping predominantly listric normal faults and ENE striking dextral faults, as a consequence of ongoing extension in the Pannonian Basin. Timing of deformation is constrained by the Ottnangian (middle Burdigalian) to middle Badenian (late Langhian) age (~ 18–14 Ma) of syn-rift deposits observed on the reflection seismic and well data. In the early post-rift stage, short lasting late Sarmatian (late Serravallian; ~ 12 Ma) contraction is registered (D6), preceding the main stage of the basin inversion.

The youngest recorded deformational event (D7) characterised by late Pannonian (late Messinian; ~ 6 Ma) to recent NNW-SSE contraction, resulted in reactivation of ENE striking dextral faults, formation of new SE striking dextral faults as well as the formation of E to ENE trending folds and reverse faults. This event is a result of the N-ward indentation and CCW rotation of the Adriatic microplate. Overall Miocene and post-Miocene deformation history of the study area is in agreement with well-known Pannonian back-arc tectonics starting in the Early Miocene.

Our results infer that the study area was affected by tectonic processes related to the different stages of the evolution of the Neotethys Ocean, opening of the Alpine Tethys Ocean, as well as the opening and inversion of the Pannonian Basin. Mesozoic tectono-sedimentary evolution of Ivanščica Mt. proves the paleogeographic affiliation of its non-ophiolitic Mesozoic structural-stratigraphic entities to the Pre-Karst unit of the Dinarides.

Data availability

All data generated or analysed during this study are included in this article.

Abbreviations

AFT:

Apatite fission track

APAZ:

Apatite partial annealing zone

BZBT:

Babin Zub back-thrust

CCW:

Counter clockwise

CSC:

Cenozoic sedimentary cover

ČMT:

Črne Mlake thrust

Dn:

Deformational event (n is the number indicating the relative age of the event where the number 1 is the oldest event)

DLS:

Dinaride Lake System

GPF:

Gotalovec-Prigorec fault

IIF:

Ivanščica Imbricate Fan

IP:

Ivanščica Parautochthon

MSWD:

Mean square of weighted deviates

n:

Number of used data

PRF:

Prigorec reverse fault

P(χ2):

Probability of obtaining chi-square (χ2) for n degrees of freedom (n is the number of crystals

SSZ:

Supra subduction zone

ŠF:

Šoštanj fault

TAI:

Thermal alteration index

VR:

Vitrinite reflectance

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Acknowledgements

László Csontos (MOL Group) and Michele Marroni (Università di Pisa) are gratefully acknowledged for their reviews and suggestions that have significantly improved the first version of the manuscript. The authors would like to thank to Matija Šimunić for providing the photo in Fig. 6h. The authors are especially grateful to the editors Daniel Marty (Naturhistorisches Museum Basel) and Stefan M. Schmid (Universität Basel) for coordinating the publishing process and additional and very helpful comments and suggestions by Stefan M. Schmid. This research was supported by the Croatian Science Foundation under the project “Revealing the Middle Triassic Paleotethyan Geodynamics Recorded in the Volcano-Sedimentary Successions of NW Croatia (GOST)” (IP-2019–04-3824).

Funding

This research was funded by the Croatian Science Foundation under the project “Revealing the Middle Triassic Paleotethyan Geodynamics Recorded in the Volcano-Sedimentary Successions of NW Croatia (GOST)” (IP-2019-04-3824).

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Matija Vukovski: conceptualization, methodology, field work (lead), analysis (structural), investigation, writing—original draft, review and editing (lead); Marko Špelić: analysis (seismic sections), writing—original draft, review and editing (equal); Duje Kukoč: field work (supporting), writing—original draft, review and editing (equal); Tamara Troskot-Čorbić: analysis (vitrinite reflectance), writing—original draft, review and editing (equal); Tonći Grgasović: field work (supporting), writing—review and editing (supporting); Damir Slovenec: writing—review and editing (supporting); Bruno Tomljenović: conceptualization, methodology, field work (supporting), writing—original draft, review and editing (supporting).

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Correspondence to Matija Vukovski.

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Vukovski, M., Špelić, M., Kukoč, D. et al. Unravelling the tectonic evolution of the Dinarides—Alps—Pannonian Basin transition zone: insights from structural analysis and low-temperature thermochronology from Ivanščica Mt., NW Croatia. Swiss J Geosci 117, 16 (2024). https://doi.org/10.1186/s00015-024-00464-5

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