- Original paper
- Open Access
Episodes of fissure formation in the Alps: connecting quartz fluid inclusion, fissure monazite age, and fissure orientation data
Swiss Journal of Geosciences volume 114, Article number: 14 (2021)
Fluid assisted Alpine fissure-vein and cleft formation starts at prograde, peak or retrograde metamorphic conditions of 450–550 °C and 0.3–0.6 GPa and below, commonly at conditions of ductile to brittle rock deformation. Early-formed fissures become overprinted by subsequent deformation, locally leading to a reorientation. Deformation that follows fissure formation initiates a cycle of dissolution, dissolution/reprecipitation or new growth of fissure minerals enclosing fluid inclusions. Although fissures in upper greenschist and amphibolite facies rocks predominantly form under retrograde metamorphic conditions, this work confirms that the carbon dioxide fluid zone correlates with regions of highest grade Alpine metamorphism, suggesting carbon dioxide production by prograde devolatilization reactions and rock-buffering of the fissure-filling fluid. For this reason, fluid composition zones systematically change in metamorphosed and exhumed nappe stacks from diagenetic to amphibolite facies metamorphic rocks from saline fluids dominated by higher hydrocarbons, methane, water and carbon dioxide. Open fissures are in most cases oriented roughly perpendicular to the foliation and lineation of the host rock. The type of fluid constrains the habit of the very frequently crystallizing quartz crystals. Open fissures also form in association with more localized strike-slip faults and are oriented perpendicular to the faults. The combination of fissure orientation, fissure quartz fluid inclusion and fissure monazite-(Ce) (hereafter monazite) Th–Pb ages shows that fissure formation occurred episodically (1) during the Cretaceous (eo-Alpine) deformation cycle in association with exhumation of the Austroalpine Koralpe-Saualpe region (~ 90 Ma) and subsequent extensional movements in association with the formation of the Gosau basins (~ 90–70 Ma), (2) during rapid exhumation of high-pressure overprinted Briançonnais and Piemontais units (36–30 Ma), (3) during unroofing of the Tauern and Lepontine metamorphic domes, during emplacement and reverse faulting of the external Massifs (25–12 Ma; except Argentera) and due to local dextral strike-slip faulting in association with the opening of the Ligurian sea, and (4) during the development of a young, widespread network of ductile to brittle strike-slip faults (12–5 Ma).
Fluid-assisted fissure-vein and cleft formation occurred in the Alps in metamorphic rocks due to fluid-assisted embrittlement under prograde, peak to retrograde metamorphic conditions at or below 450–550 °C and 0.3–0.6 GPa (e.g., Diamond & Tarantola, 2015; Heijboer et al., 2003a, 2006; Mullis & Tarantola, 2015; Mullis, 1974, 1976a, 1976b, 1983, 1991, 1996, 2011; Mullis et al., 1994; Poty, 1969; Poty et al., 2007, 2018; Rauchenstein-Martinek et al., 2016; Sharp et al., 2005). The formation of these structures was related to the prevailing local stress fields induced by the collision of continental microplates with the European continental plate (e.g. Handy et al., 2010). Generated fissures are most commonly oriented perpendicular to foliation and lineation of their host rocks. Interaction of fluid-filled clefts with the surrounding rock led to dissolution of minerals in the wall rock and mineral precipitation in the fissures (e.g., Heijboer et al., 2006; Mullis, 1976a, 1995, 2011; Mullis & De Capitani, 2000; Mullis & Wolf, 2013; Mullis et al., 1994; Sharp et al., 2005; Weisenberger & Bucher, 2011). Fissures became either completely filled and became mineral veins, or were enlarged by subsequent tectonic activity to form fluid-filled dm- to m-sized clefts, in which large crystals grew from cleft formation down to temperatures < 200 °C. As long as deformation continued, minerals in fluid-filled clefts reacted to deformation via dissolution–precipitation cycles due to disequilibrium between fluid, rock wall and mineral assemblage within the cleft (Bergemann et al., 2019, 2020; Heijboer et al., 2003a, 2006; Mullis, 1976a, 2011; Ricchi et al., 2019, 2020a; Wolf & Mullis, 2012). Thus, minerals did not only grow following the initial fissure formation but continued to grow, to crystallize newly or to dissolve during subsequent deformation stages or other causes leading to chemical disequilibrium. Fissures forming in schists during prograde metamorphism became usually deformed until they formed foliation-parallel (e.g., Miron et al., 2013), more or less boudinaged veins. However, these veins provided important competence contrast, acting as an incipient point for retrograde formation of open fissures.
In contrast to the surrounding country rock and veins, fluid-filled fissures and clefts remained highly reactive at low temperature due to the presence of fluid, permitting registration of deformation steps through mineral growth or recrystallization (e.g., Bergemann et al., 2018, 2019, 2020; Berger et al., 2013; Mullis, 1976a, 1976b, 2011; Mullis & Wolf, 2013; Mullis et al., 2001a, 2001b; Ricchi et al., 2019, 2020a).
Fissure quartz fluid inclusions similarly revealed growth events related to tectonic activity and have been studied systematically in the Alps (Bernard, 1978; Cesare et al., 2001; Fabre et al., 2002; Heijboer et al., 2003a, 2003b, 2006; Kandutsch et al., 1998; Marshall et al., 1998a, 1998b; Miron et al., 2013; Mullis, 1975, 1976a, 1976b, 1983, 1991, 1995, 1996, 2011; Mullis et al., 1994, 2002, 2017; Poty, 1969; Rauchenstein-Martinek et al., 2016; Rossi & Rolland, 2014; Tarantola et al., 2007, 2009). A compilation of the dominant fissure quartz fluid inclusion type compiled in Poty et. al. (2007) and complemented with additional data is shown in Fig. 1.
Fissure minerals are typically mm to cm in size, and easy to separate for further geochronological studies. This is the reason why potassium feldspars and micas from different localities were among the first minerals used for trying to date Alpine metamorphism (Purdy & Stalder, 1973). However, in many cases the authors found that the radiometric system of the fissure mineral was disturbed. For this reason, only a few meaningful fissure mineral ages existed (Köppel & Grünenfelder, 1975; Peretti et al., 1981; Purdy & Stalder, 1973; Rauchenstein-Martinek, 2014; Rolland et al., 2008; Sharp et al., 2005) before fissure monazite dating.
Fissure monazite most commonly crystallizes in Ca-poor lithologies (meta-pelites, meta-arenites, meta-granitoids). Once formed, diffusion in monazite is negligible under prevailing P–T conditions (Cherniak et al., 2004; Gardés et al., 2006, 2007) and hydrothermal monazite hence dates crystallization. Chemically and isotopically homogeneous crystals indicate a single, rapid growth episode (e.g., Grand’Homme et al., 2016a). Though crystals showing different growth domains indicative of successive growth episodes are most common. However, further hydrothermal processes can affect monazite after its initial crystallization (e.g., Janots et al., 2012). Alteration and dissolution-reprecipitation can lead to resetting of the monazite Th–U decay systems in parts or the entire crystal (e.g., Grand’Homme et al., 2016b; Seydoux-Guillaume et al., 2012). In other cases, parts or entire grains display a patchy zoning due to dissolution-reprecipitation processes (e.g., Ayers et al., 1999; Bergemann et al., 2019, 2020; Gnos et al., 2015; Grand’Homme et al., 2016b; Ricchi et al., 2019, 2020a), which is especially frequent in the Lepontine and Tauern metamorphic domes. The replacement process is associated with element fractionation resulting in crystal zones with often distinct U/Th values (Bergemann et al., 2017; Grand’Homme et al., 2016a, 2016b; Seydoux-Guillaume et al., 2012).
Although thermochronological data exist now for most parts of the Alps, constraining its exhumation history (e.g., Bertrand et al., 2015; Fox et al., 2016; Rosenberg & Berger, 2009; Vernon et al., 2008), it has been shown that Th–Pb fissure monazite domain ages, in some cases in combination with fluid inclusion data, are linkable to tectonic events (e.g., Bergemann et al., 2017, 2018, 2019, 2020; Berger et al., 2013; Janots et al., 2019; Ricchi et al., 2019, 2020a, 2020b). In some cases deformation is associated with fluid advection (e.g., Bergemann et al., 2019; Janots et al., 2019). On the other hand, since cleft monazite starts to crystallize typically ≤ 400 °C (much below the monazite closure temperature (Cherniak et al., 2004), it can be utilized to constrain successive deformation activity in fault and damage zones under low grade metamorphic conditions (e.g., Bergemann et al., 2017, 2018, 2019, 2020; Berger et al., 2013; Ricchi et al., 2019, 2020a, 2020b). Compositional (e.g. Th/U; Grand’Homme et al. 2016a) and age zoning in hydrothermal monazite is attributed to re-equilibration at different P-T-X conditions, initiated by tectonic events. They are thus considered as syntectonic growth domains. Fissure monazite growth starts characteristically towards the end of the quartz growth, as shown by a well-investigated Alpine fissure from Zinggenstock in the Aar Massif (Mullis, 1995, 1996), where monazite occurs as solid inclusion in late quartz and started crystallizing at ≤ 380 °C. Most common is growth of monazite on the surface of quartz or adularia. This suggests that monazite generally provides a minimum age for fissure formation, except where its crystallization can be directly linked to the formation of a new fissure generation (e.g. Bergemann et al., 2017, 2019; Ricchi et al. 2020a).
Beneath ~ 270 °C (methane and higher hydrocarbon (HHC) fluid zones; Fig. 1; see below), tectonic movements may cause monazite or florencite (CeAl3(PO4)2(OH)6) growth. The latter has been reported from fissures in the Urals (e.g., Repina, 2010). Neither monazite nor florencite have been found in Alpine open fissures in the methane or HHC zones (Fig. 1). For this reason, crystallization ages are lacking for these fluid zones (Figs. 1 and 2).
A compilation of the oldest growth domains of dated fissure monazite is given in Fig. 2. These ages will be used here as a proxy for distinguishing episodes of fissure formation in different parts of the Alps since geochronological systems permitting a direct dating of fissure formation are lacking. Thus intersecting temperatures derived from K/Na thermometry of the earliest fluid inclusion population (Poty et al., 1974) with the regional cooling path remains a good approach to estimate the fissure formation age (e.g., Mullis, 1996).
A compilation of best estimates for σ3 axes of paleostress orientations in the Alps, based on brittle deformation data obtained by many authors was provided in Bertrand and Sue (2017). These data can be compared with measured fissure orientations.
The aim of this study is to combine published information from fissure monazite dating, quartz morphology and fissure orientation in order to attribute existing quartz fluid inclusion data to different tectono-metamorphic episodes of fissure formation.
2 Tectonic and metamorphic setting of Alpine fissures
The European Alps, consisting of the E–W trending Eastern Alps and the arcuate Western Alps are the result of two orogenies. The first is Cretaceous in age, and the second Cenozoic (e.g., Froitzheim et al., 1996). The Alps are characterized by a deformed stack of large-scale nappes derived from the Adriatic continental plate, the Alpine Tethys ocean (including the Briançonnais continental basement) and the European continental plate (e.g., Schmid et al., 2004; Schuster, 2015; Stampfli et al., 1998). During both orogenies the metamorphic peak followed nappe stacking and was followed by exhumation of metamorphic rocks (e.g., Engi et al., 2004; Oberhänsli et al., 2004; Schuster et al., 2004). The Cretaceous orogeny can be studied inside the Austroalpine and parts of the Austroalpine/Alpine Tethys contacts of the Eastern Alps (e.g., Schmid et al., 2004; Fig. 1). An overview of the age range of the eo-Alpine (Cretaceous) and Alpine (Neogene) peak metamorphism is provided in Bousquet et. al. (2012a), and for the subduction related HP-LT metamorphism in Thöni (1999) and Berger and Bousquet (2008).
Abundant deformed quartz veins in metasedimentary rocks indicate that fissure formation is frequent during prograde metamorphism (e.g., Heijboer et al., 2003a; Mullis & Tarantola, 2015; Yardley, 1983), but fissures generally do not remain open and reactive in such rocks during progressive deformation and are eventually transposed into the foliation plane, and monazite enclosed in quartz cannot react with the fluid anymore. Open fissures that may reach dimensions of meter-sized clefts (e.g., Stalder et al., 1998) formed during peak to retrograde metamorphism. In the field, open fissures developing roughly perpendicular to foliation and lineation are most common at higher grade. At lower grade en-echelon fissures may occur (Mullis, 1974, 1976b).
Tectonic movements causing disequilibrium between host rock, mineralizing fluid and cleft minerals lead to dissolution/precipitation cycles (Bergemann et al., 2018, 2019, 2020; Grand’Homme et al., 2016a, 2016b; Mullis, 1976a, 2011; Mullis & De Capitani, 1997; Mullis et al., 2001a, 2001b; Ricchi et al., 2019, 2020a, 2020b; Wolf et al., 2015). In many cases, tectonic activity also leads to cracking and deformation of cleft minerals or detachment of fragments from the rock wall (Mullis, 1996, 2011; Mullis et al., 2001a, 2001b; Wolf & Mullis, 2012). Primary/secondary fluid inclusion populations are not only comparable within one cleft, but are also regionally clustered (Barlier, 1974; Frey et al., 1980a, 1980b; Mullis, 1976a, 1979, 1983, 1987; Poty, 1969; Poty et al., 1974; Stalder & Touray, 1970).
3 Fissure- and cleft-filling fluid
Detailed studies by Barlier (1974), Mullis (1979, 1983), Frey et. al. (1980a, 1980b), Mullis et. al. (1994), and Rauchenstein-Martinek et. al. (2016) have shown that earliest fluid entrapped in fluid inclusions in fissure quartz, but also in metamorphic quartz (e.g., Touret, 1980), changes systematically with the regional metamorphic grade. The fluid inclusion studies also showed that crystallization in open fissures in amphibolite facies rocks or in retrogradely overprinted high-pressure rocks only formed under retrograde greenschist facies conditions.
A fluid composition zonation through the Central Alps could be established by Frey et. al. (1980a, 1980b), Mullis (1983) and Mullis et. al. (1994): at low- and medium-grade diagenetic conditions the saline aqueous fluid entrapped in fissure quartz is characterized by ~ 1 to > 80 mol% higher hydrocarbons (HHC zone; Barlier, 1974; Frey et al., 1980a, 1980b; Mullis et al., 1994; Touray et al., 1970), indicating formation temperatures and pressures of ≤ 200 °C and ≤ 0.12 GPa respectively (Mullis, 1979). In the upper diagenetic and low-grade anchizone, fluid inclusion composition is generally dominated by ~ 1 to ≥ 90 mol% methane (CH4 zone; Barlier, 1974; Frey et al., 1980a, 1980b; Mullis, 1976a, 1979, 1983; Mullis et al., 1973, 1994; Stalder & Touray, 1970). These methane-bearing to methane-rich fluid inclusions were trapped at temperatures and pressures between ≥ 200 and 270 ± 5 °C and between ≥ 0.12 and ≤ 0.18 GPa, respectively (Mullis, 1979, 1987; Tarantola et al., 2009). The metamorphic grade/fluid zonation correlation has been verified for very low-grade conditions by comparing fluid inclusion homogenisation temperatures with illite crystallinity and vitrinite reflection measurements in diagenetic and low-grade anchizonal terrains between 50 and 270 °C in the external parts of the Central Alps (Mullis et al., 2002, 2017). Upper anchizone, greenschist (and greenschist-facies overprinted blueschist and eclogite) facies regions are dominated by saline aqueous fluid (H2O-zone) (~ 80 to > 99 mol% H2O; Frey et al., 1980a, 1980b; Mullis et al., 1994; Poty, 1969; Poty & Stalder, 1970; Poty et al., 1974; Rauchenstein-Martinek et al., 2016). Finally, upper greenschist, amphibolite (and amphibolite-facies overprinted eclogite) facies regions are dominated by saline aqueous-carbonic fluid (CO2 zone) (~ 10 to > 60 mol% CO2; Frey et al., 1980a; Hasenberger, 1996; Heijboer et al., 2006; Kandutsch, 1989; Mullis, 1983; Mullis et al., 1994; Proce et al., 2015; Rauchenstein-Martinek, 2014; Rauchenstein-Martinek et al., 2016; Touret, 1980; Weninger, 1981).
It is interesting to note that the fluid produced around the metamorphic peak during the Tauern and Lepontine dome formations also dominates the fissure fluid composition during fissure formation under retrograde metamorphic conditions. This means, that in an amphibolite facies metamorphic terrain, fissures forming under upper greenschist facies conditions are filled with a fluid that is more or less characteristic of the amphibolite facies metamorphic grade and CO2-enriched (Fig. 1). Fissure fluids in amphibolite facies overprinted eclogites of the Austroalpine Saualpe-Koralpe region and the Western Alps are similarly CO2-enriched.
Although fissure fluids are buffered by the host rock (e.g., Hoernes & Friedrichsen, 1980) and clefts usually behave as a more or less closed system upon deformation, there may be opening at times during exhumation, leading to loss or influx of fluid from external sources (e.g., Mullis, 1983, 1996; Mullis et al., 1994; Poty, 1969).
4 Linking fluid type with quartz habit
The prevailing fluid has also a remarkable effect on the fissure quartz habit (e.g., Kandutsch et al., 1998; Mullis et al., 1994; Mullis, 1976a, 1983, 1991; Poty, 1969; Stalder & Touray, 1970). Judging by the fluid zonation in mono-metamorphic sedimentary rocks, fissure quartz changes systematically its morphology with changing fluid zone (e.g., Mullis et al., 1994; Fig. 3) and increasing metamorphic grade of the host rock.
In the HHC zone (≤ 200 °C), freely grown quartz is short prismatic and is often overgrown by sceptre quartz. Bipyramidal quartz can also be observed. In oil rich fluids, fissure quartz tends to develop a steep rhombohedral habit (Mullis, 1991; Mullis et al., 1994; Fig. 3). All quartz crystals of the HHC zone are generally a few millimetres in size.
In the CH4 zone, that covers the upper diagenetic and low-grade anchizone (T ≥ 200 °C to ≤ 270 °C; Fig. 3), prismatic, sceptre (more rarely bipyramidal) and skeletal (‘window’ shaped) quartz is characteristic. Water-methane unmixing (immiscibility) causes fast growth along corners and edges, responsible for sceptre and ‘window’ shaped quartz growth (Fig. 3; Mullis, 1976a, 1991; Mullis et al., 1994).
In the H2O zone covering anchizonal and lower greenschist facies metamorphic conditions (≥ 270 °C to ~ 450 °C), fluids are hydrous, saline and contain < 10 mol% of dissolved CO2. Quartz crystallizing in such a fluid is prismatic in shape, shows complex macro-mosaic twinning (Friedlaender, 1951) and characteristic sutures on prism faces (Fig. 3).
In zones with prolonged tectonic activity, such as nappe contacts or the interface of crystalline basement rocks with the overlying metasedimentary cover of sub-greenschist metamorphic conditions (≥ 270 °C to ~ 350 °C), lamellar quartz of Dauphiné habit (Bambauer et al., 1961) characteristically forms. The Dauphiné habit is characterized by the development of one pyramid face growing much larger than the other five faces (e.g., Jourdan et al., 2009; Kandutsch & Wachtler, 2000; Kürsteiner et al., 2015; Mullis, 1980, 1991; Mullis & Ramseyer, 1996; Poty, 1969; Soom, 1986; Fig. 3). In some cases, the disappearance of prism faces towards the pyramid of quartz leads to the Muzo habit (Gansser, 1963; Fig. 3) that has been reported from several localities of the Eastern Alps (e.g. Glas, 1992; Hasenberger, 1996; Kandutsch, 1989; Kandutsch & Wachtler, 2000; Rykart, 1995).
In the CO2 zone Tessin habit quartz is omnipresent and characterized by the predominance of steep pyramidal faces over prism faces giving the quartz a pointed shape (Fig. 3). Characteristic sutures occur on prism/steep pyramidal faces. This habit is most pronounced in fissures of meta-sedimentary rocks that underwent high-grade greenschist or amphibolite facies metamorphism (Frey et al., 1980a; Hasenberger, 1996; Kandutsch, 1989; Kandutsch et al., 1998; Lukscheiter & Morteani 1980; Mullis, 1991, 1996; Mullis et al., 1994). Quartz in granitoid lithologies of comparable metamorphic grade and with a CO2 content of > 2 to < 10 mol% CO2 (Mullis et al., 2001a, 2001b), is generally less pointed but displays a mix between prismatic and steep pyramidal faces leading to a characteristic horizontal striation on the prism faces. Both, Tessin habit quartz and prismatic quartz with steep pyramidal faces show macro-mosaic twinning (Friedlaender, 1951) and sutures on their prism faces (Fig. 3).
Fluid immiscibility in the CO2-zone (Mullis, 1983; Mullis et al. 1994) and late infiltration of a CO2-enriched fluid in the CO2 and water zone (Mullis et al., 1994; Poty, 1969) at temperatures between ~ 330 and 250 °C lead to scepter quartz overgrowths (often amethyst) on both, Tessin habit and prismatic quartz, respectively (e.g., Burgsteiner, 2004; Hossfeld, 1977; Mullis, 1983; Mullis & Ramseyer, 1996; Mullis et al., 1994; Poty, 1969; Stalder et al., 1998; Wagner et al., 1972). Amethyst shows lamellar growth.
Along a section showing increasing Barrow-type metamorphic grade, this supports the preliminary conclusion that metamorphic grade, fluid composition and quartz habit (Fig. 3) are directly linked.
5 Fissure monazite ages and fissure orientation
A large and homogeneous set of cleft monazite growth domain ages covering most parts of the Alps is now available (Bergemann et al., 2017, 2018, 2019, 2020; Berger et al., 2013; Gasquet et al., 2010; Gnos et al., 2015; Grand’Homme et al. 2016a, 2016b; Janots et al., 2012; Ricchi et al., 2019, 2020a, 2020b; Fig. 2). Recalculated values for some monazites from the Aar Massif and the Gotthard Nappe are provided in the supplement (Additional file 1: Table S1 and Fig. S1). In most cases, fissure monazite crystallization does not date fissure formation, because it starts to crystallize typically < 300–350 °C (e.g., Bergemann et al., 2019; Gnos et al., 2015; Mullis, 1996; Ricchi et al.,2020a), although growth at higher temperature was recently reported (Janots et al., 2019). Monazite characteristically crystallizes a few million years after cleft formation, towards the end of the fissure quartz growth (e.g., Gnos et al., 2015; Mullis, 1996). Only in some cases was it possible to revisit the exact monazite find location to collect complementary structural data. A compilation of fissure and cleft orientations for areas where fissure monazite was reported is provided in Fig. 4. Gasquet et. al. (2010) were the first to date fissure monazite derived from an older generation of horizontal and a younger generation of vertical fissures in the Belledonne and Pelvoux massifs, using the LA-ICP-MS technique. This yielded ages between 17.6 ± 0.3 and 5.4 ± 0.5 Ma. They could show that ages between 11 and 5 Ma were related to two stages of dextral strike-slip faulting. Janots et. al. (2012) used the SIMS technique, providing higher spatial resolution, and dated growth domains in two grains from horizontal fissures located in the Aar Massif and the Gotthard Nappe. They obtained ages of 15.2 ± 0.3 to 13.5 ± 0.4 Ma. One grain showed a stage of dissolution between two growth domains. Berger et. al. (2013) and Bergemann et. al. (2017) used fissure monazite for dating a younger generation of vertical fissures in the Aar Massif at 11.75 ± 0.41 to 6.32 ± 0.20 Ma and could show that dextral strike-slip faulting in the Aar Massif occurred roughly coeval with strike-slip faulting in the Belledonne Massif (Fig. 1). Systematic studies by Bergemann et. al. (2019, 2020) covering the Mont Blanc/Aiguilles Rouges massifs and the Lepontine Dome and by Ricchi et. al. (2019, 2020a) covering the Aar Massif/Gotthard Nappe and the entire Tauern Window confirmed the widespread formation of late, vertical fissures that formed in association with sinistral (Tauern Window) and dextral strike-slip faulting (Simplon-Rhone fault and faults in the Aar, Gotthard, Mont Blanc, Aiguilles Rouges, Belledonne and Pelvoux massifs) starting at ~ 12 Ma. Sinistral strike-slip faulting in the Tauern Window resulted in vertical fissures (Ricchi et al., 2020a), oriented subparallel to the older generation (Fig. 4). Coeval dextral strike-slip faults in the Western Alps have corresponding vertical fissures that strike SE in the Aar Massif and E–W in the Mont Blanc, Aiguilles Rouges, Belledonne and Pelvoux massifs (Fig. 4). From this time on, episodic reactivation of the strike-slip faults occurred (Bergemann et al., 2017, 2019; Berger et al., 2013; Gasquet et al., 2010; Ricchi et al., 2019, 2020a, 2020b; Schneider et al., 2013), with the youngest recorded fissure monazite domain age is ~ 5 Ma (Bergemann et al., 2020). Present day faulting shows the same kinematics and inferred stress field, indicating constant stress fields over the last several millions of years (e.g., Bertrand & Sue, 2017).
In the Tauern and Lepontine metamorphic domes, fissure formation is very common during extensional unroofing, and the oldest growth domains record an age range of 21.7 ± 0.4 to 11.92 ± 0.26 Ma (Bergemann et al., 2020; Gnos et al., 2015; Ricchi et al., 2020a; Fig. 2). Fissures are vertical, N to NE striking in the Eastern, and SE striking in the Western Tauern Window and mostly NW striking in the Lepontine structural and metamorphic dome (Fig. 4).
At the same time fissure monazite crystallization also occurred in the external massifs and, except for Argentera, in association with reverse faulting (Bergemann et al., 2019; Gasquet et al., 2010; Janots et al., 2012; Ricchi et al., 2019). For this reason, fissures of this generation are oriented roughly horizontal in the Aar Massif/Gotthard Nappe, the Mont Blanc/Aiguilles Rouges massifs and the Belledonne/Pelvoux massifs (Fig. 4).
The orientation of early vertical fissures in high-pressure regions of the Western Alps differs from those of the external massifs and the Lepontine dome. The fissures were dated to 36.6 ± 0.6 Ma to 30.2 ± 0.5 Ma in the Briançonnais Unit and strike regionally quite homogenously SE (Grand’Homme et al. 2016a; Ricchi et al., 2020b; Fig. 4). However, the fissures located just southwest of the Simplon detachment fault may have been affected by younger tectonic movements during the Lepontine dome formation.
Vertical fissures associated with dextral strike-slip faults are E striking in the Briançonnais and ENE striking in the Argentera Massif (Fig. 4). These fissures are older than those forming after ~ 12 Ma during dextral strike-slip faulting in all other external massifs.
At the other end of the Alps, much older, eo-Alpine fissure monazites were found in Austroalpine units located east of the Tauern Window, where monazite crystallization occurred around 90 Ma in association with strike-slip faulting (Bergemann et al., 2018), during exhumation of the Koralpe-Saualpe region. These fissure monazites partially recrystallized in association with extensional tectonics associated with the formation of the Gosau basins between ~ 90 and 70 Ma.
In general, very few data exist for the Austroalpine units and no data are available for the region west of the Tauern Window. In the Koralpe-Saualpe region Cretaceous fissures are vertical and roughly ENE striking, whereas north of it, in the Greywacke Zone, they also show a N–S orientation (Fig. 4).
Monazite ages have been compiled in Fig. 2 (see figure caption for references). They are attributed to fissure generations that formed: (1) During exhumation of different Austroalpine units in the Cretaceous (eo-Alpine), (2) during exhumation of the Penninic high pressure units, (3) during metamorphic dome formation, steep reverse faulting in the external massifs and during early strike-slip faulting affecting the high pressure units of the Western Alps and the Argentera Massif, and (4) during late strike-slip faulting affecting the metamorphic dome regions and all external massifs, except Argentera. All available monazite crystallization domain ages and spot age ranges are compiled in Table 1. A compilation of fissure and cleft orientations for areas where fissure monazite was reported is provided in Fig. 4.
The formation of open fissures and fissure monazite crystallization occurs in the upper crust at conditions at or below 450–550 °C and 0.3–0.6 GPa (e.g., Diamond & Tarantola, 2015; Heijboer et al., 2003a, 2006;Mullis, 1974, 1976a, 1976b, 1983, 1991, 1996, 2011; Mullis & Tarantola, 2015; Mullis et al., 1994; Poty, 1969; Poty et al., 2007, 2018; Rauchenstein-Martinek et al., 2016; Sharp et al., 2005), in association with regional scale deformation or localized faulting.
6.1 Fluid inclusion type, metamorphic grade and quartz habit
In most open fissures the fluid derived from the surrounding rock and formed at or near the peak of metamorphism. For this reason it changes systematically with regional metamorphic grade (Fig. 1), causing a change in the quartz habit with changing fluid zones. There are cases (e.g., Bedretto Valley, Ticino; Mullis, 1991) where late tectonic movements produced fissures that are oriented parallel to an earlier generation, but can easily be recognized due to its different quartz habit. Such occurrences help to recognize discrete faults, where the corresponding lineation is only developed on few, narrow fault planes. Complemented with fluid inclusion thermometry (Fig. 3) the quartz habit is very useful for constraining the temperature of formation of the fissure.
6.2 Alpine fissure formation over time
The Alps are the result of two major orogenies (e.g., Froitzheim et al., 1996), Cretaceous and Cenozoic in age. Different Alpine units underwent exhumation at different times, and hence, fissure formation occurred in association with different tectonic settings. Crosscutting fissure relationships may locally be found in the external massifs (Aar, Gotthard, Mont Blanc, Aiguilles Rouges, Belledonne, Pelvoux (e.g., Ricchi et al., 2019; Steck, 1968). In rare cases, multiple deformation results in complex fissure shapes or intersecting fissures (e.g., Ricchi et al., 2019; Steck, 1968). In other areas, fissures that formed at different episodes show subparallel orientations. Meaning that often only the study of the surrounding rock fabric, in combination with the deformation history, may provide additional clues about the formation and evolution of a fissure. Due to such tectonic reactivations, fissure mineral growth is thus in many cases the result of multiple, more or less pronounced, regional deformation events (Burkhard & Kerrich, 1988; Heijboer et al., 2003b; Mullis, 1975, 1976b, 1996, 2011; Mullis et al., 2001a, 2001b; Wolf & Mullis, 2012).
P–T estimates based on quartz fluid inclusions indicate that in the higher hydrocarbon and methane fluid inclusions zones (Fig. 1) and in parts of the water zone located in lower greenschist facies rocks, fissure formation occurred roughly coeval with the metamorphic peak. This concerns the thrust European foreland, Helvetic nappes, the most external parts of the External Massifs, and probably also parts of the Australpine regions (Fig. 1). Fissures located in higher grade greenschist and amphibolite facies rocks in the water and CO2 fluid zones formed after nappe stacking and metamorphic peak under retrograde greenschist facies conditions. This concerns large parts of the External Massifs, the Penninic nappes, and in the Austroalpine nappes the Koralpe-Saualpe region and probably also other regions. In strike-slip settings, fissure formation is related to tectonic activity under low grade greenschist facies to very-low grade metamorphic conditions.
The quartz fluid inclusion map shown in Fig. 1 shows that fissures are rare in some regions, but abundant in others. In the Austroalpine units, “rareness” may be linked to the lack of knowledge of discovered and investigated fissures, weathering and vegetation cover. The rareness of clefts in the southeastern sector of the Lepontine dome (Fig. 1) indicates that fluids were either efficiently drained or not available on the melt bearing level of the dome (e.g., Burri et al., 2005), or the area highly overprinted due to large and non-localized deformation in this region. The latter is most likely, due to the frequent high-grade quartz veins in this area (i.e., sillimanite/kyanite-quartz veins; Allaz et al., 2005; Beitter et al., 2008), possibly indicating fluid escape in veins at amphibolite conditions.
Fissure monazite dating shows that fissure formation in association with metamorphism and tectonic movements occurred several times during the Alpine evolution (Fig. 5). In comparison with published orogenic timetables of the Alps (e.g., Pfiffner (2015) and references therein, fissure formation occurred after main thickening and nappe development, mainly during post-nappe deformation. These post-nappe deformation stages were mainly related to exhumation processes. A special example of exhumation process occurred in the Tauern Window, where large scale folding was contemporaneous with normal faulting and strike-slip movements (Rosenberg et al., 2018). The vertical fissures developed mainly during these movements (Brenner-Katschberg phase in Pfiffner (2015)). Post-nappe deformation in the Central Alps included large scale folding and normal faulting (e.g., Chièra folding, Forcola- and Simplon normal faulting). In the external massifs (Aar Massif/Gotthard Nappe, Mont Blanc/Aiguilles Rouges Massifs and Belledonne/Pelvoux Massifs) fissure formation occurred during phases of dominant reverse faulting (e.g., Handegg deformation phase in the Aar Massif; Herwegh et al., 2020; Ricchi et al., 2019). This phase is related to the well-known post-nappe deformation of the Helvetic units (Ruchi phase in the east, Kiental phase in the west; Pfiffner 2011, 2015). In the very-low grade metamorphic European foreland sediments fissures show two main orientations (Fig. 4). Their formation is related to late detachments and extensional movements in association with the exhumation of the external massifs. In the high-pressure dominated regions of the Western Alps, fissure formation occurred also during exhumation and Barrow-type metamorphic overprinting of the high-pressure units. In the Austroalpine units, eo-Alpine fissures formed in the Koralpe-Saualpe region during the exhumation following crustal thickening and Barrow-type metamorphism. The orientation (Fig. 4) indicates that they formed during the D3 deformation phase of Kurz and Fritz (2003). Fissures that formed in association with strike-slip faulting belong to the youngest generation in all areas.
Fissure monazite growth domain ages constrain the following episodes of fissure formation.
6.2.1 Cretaceous (eo-Alpine) episodes
This time range covers the eo-Alpine (Cretaceous) oceanic and continental subduction followed by continental thickening (e.g., Schuster et al., 2004; Thöni, 1999) including HP-LT and Barrovian metamorphism (e.g., Bousquet et al., 2012b; Frey et al. 1999). Locally, fissures, which formed at the latest around ~ 90 Ma (Bergemann et al., 2018; Fig. 5) are preserved. Depending on the metamorphic grade reached, fissure fluid is dominated by CO2 or saline water (Fig. 6a). Fissures and clefts are vertical and ENE striking in the metamorphic regions of Saualpe-Koralpe (Koralpe-Wölz and Silvretta-Sekau Nappe Systems; e.g., Schuster et al., 2013) but very few data are available. Fissures have also been reported from the Pohorje ultra-high pressure unit (Niedermayr, 1992) and presumably formed at a similar time. A paleogeographic reconstruction from Handy et. al. (2010), displaying in which tectonic situation Cretaceous fissure formation occurred, is shown in Fig. 7.
In the region south of the eastern Tauern Window, thermochronology shows Cenozoic metamorphic overprinting (e.g., Rosenberg & Berger, 2009; Rosenberg et al., 2015, 2018). Although we cannot exclude that Cenozoic fissures may exist in this area, we attribute these fissures to have formed during the Cretaceous orogeny (Fig. 6). Unfortunately, data are also lacking for the Austroalpine regions west of the Tauern Window. However, mica cooling ages (Satir, 1975; Thöni, 1981) indicate an eo-Alpine metamorphism for this region, implying fissures in this area to be also Cretaceous in age.
Following exhumation, extensional movements along normal faults led to subsidence and formation of the Gosau basins in the Eastern Alps between 90 and 70 Ma (e.g., Wagreich, 1995). Locally, existing fissure monazite recrystallized during this tectonic activity (Bergemann et al., 2018). Quartz fluid inclusion data attributed to this deformation stage are shown in Fig. 6a.
6.2.2 Cenozoic episodes
The subduction of the European oceanic and following continental lithosphere produced the different HP-LT metamorphism in the Western Alps (e.g., Agard et al., 2003; Berger & Bousquet, 2008). Slab breakoff and underthrusting of (ultra)high-pressure metamorphic units by the European continental crust caused rapid post-nappe exhumation, decompression and metamorphic overprinting of the HP assemblages at greenschist to amphibolite facies conditions (e.g., Manzotti et al., 2018; Schenker et al., 2015). Schenker et. al. (2015) proposed that decompression of the HP Dora Maira, Monte Rosa, Gran Paradiso, Adula-Cima Lunga and Zermatt-Saas units down to ~ 1 GPa occurred within < 2 Ma. The associated fluid-assisted fissure formation may have been triggered by this decompression tectonics. The vertical to sub-vertical fissures in the HP Briançonnais and Piemontais units are all roughly NNW-striking (Fig. 4) indicating an ENE striking of σ3. Fissures of this age show a similar orientation from the Zermatt-Saas to the Dora Maira regions (Fig. 4) and are oriented perpendicular to the prevailing flat foliation and lineation. This probably indicates that the younger counterclockwise rotations of units (Collombet et al., 2002; Maffione et al., 2008; Thomas et al., 1999) related to the opening of the Ligurian basin mainly affected units located south of Dora Maira/Pelvoux regions.
Monazite from fissures in these HP-LT regions of the Western Alps yielded crystallization ages of 36–30 Ma (Fig. 2). A paleogeographic reconstruction from Handy et. al. (2010) for 35 Ma showing the location of fissure formation in the exhuming Briançonnais units is given in Fig. 7. Faults active at 32 Ma are shown in Fig. 8. The prevailing fissure fluid is saline water, in the Dora Maira unit also CO2-rich (Fig. 6b). Fissure formation is also common in rodingites in ultramafic units of the Piemontais (e.g., Piccoli et al., 2007) and probably occurred roughly coevally.
Despite the lack of fissure monazite data from HP-LT regions between the Lepontine and Tauern domes (Fig. 2), radiometric and fission track data indicate that the decompression, and hence fissure formation likely occurred between 35 and 27 Ma in the Engadine Window, between 32 and 29 Ma in the Hinterrhein region (Wiederkehr et al., 2008) and between 33 and 32 Ma in the Adula Nappe (Liati & Gebauer, 2009). The areas of decompression from the HP-LT into greenschist facies (locations without a Barrovian overprint) have a different fissure record than the areas with a Barrovian overprint. However, in some areas, the “decompression greenschist” and the “Barrovian greenschist” are difficult to distinguish (Wiederkehr et al., 2008). Fissure monazites VALS and TAMB1 from the Adula and Tambo nappes analyzed by Bergemann et. al. (2020) and listed in Table 1 crystallized in association with the exhumation of the Lepontine Dome and not during the exhumation of the high-pressure rocks.
Even though fissure mineral crystallization ages are lacking fot the western boundary of the Autroalpine to the Penninic units, fissures shown in Fig. 4 are interpreted to have formed in association with exhumation of high-pressure overprinted rocks.
The collision of the western Adria (Ivrea indenter) with Europe led to upward movements of the central part of the Alps in combination with strike slip movements along the Insubric Line (Schmid et al., 1989; Fig. 8). In the Lepontine dome region this led to the formation of large scale-upright asymmetric antiforms, an E–W extension and doming, with fissure orientations (Fig. 4) most commonly perpendicular to the foliation and rock lineation. This tectonic evolution seems connected to the counter-clockwise rotation of Adria. Rotation has been related to the development of basins and oceanic crust west of this part of Adria (see van Hinsbergen et al., 2020) and includes the development of the Provençal basin, Ligurian basin and the Gulf of Lyon, which developed from the Oligocene to today (e.g., Dewey et al., 1989; Facenna et al., 2001; Schmid et al., 2017; van Hinsbergen et al., 2020). The here interesting stage of oceanization in the Liguro-Provençal Basin occurred between 21 and 16 Ma and was accommodated by a ~ 50° counter-clockwise rotation of Sardinia–Corsica relative to Europa (Gattacceca et al., 2007). Paleomagnetic data (Collombet et al., 2002; Maffione et al., 2008; Thomas et al., 1999) show that this is connected to the 47–117° counterclockwise rotation of blocks inside the Liguran Alps and the area of Piemonte. This tectonic of the southern part of the Western Alps is related to stage 3 of forming the Western Alpine Arc in the sense of Schmid et. al. (2017). The related fissure formation occurs in association with greenschist and sub-greenschist facies ductile to brittle, dextral shear zones (e.g., Corsini et al., 2004). Corresponding fissures in the Argentera Massif are vertical and NE oriented (Fig. 4), and monazite yielded domain ages of 20.6 ± 0.3 Ma (Grand’Homme et al., 2016a, 2016b) to 14.4 ± 0.5 Ma (Ricchi et al., 2020b; Fig. 5). Dextral faulting along another shear zone in the Argentera Massif had started at 33.6 ± 0.6 Ma (Sanchez et al., 2011), thus during exhumation of high-pressure units in the Western Alps. However, the fissure monazite record indicates that fault activity seems to have ceased at 14.4 ± 0.5 Ma (Ricchi et al., 2020b). Faults considered active at 21 and 17 Ma are shown in Fig. 8.
Using the paleomagnetic data for backrotation brings the strike-slip faults of the Argentera Massif to a N–S orientation and this would indicate that corresponding fissures were originally E–W striking.
At ~ 22 Ma steep reverse faulting and formation of horizontal fissures and clefts started in the Mont Blanc Massif (e.g., Leloup et al., 2005; Poty et al., 2018). This reverse faulting (and related fissure generation) may have started at a slightly different age in the Aiguilles Rouges, Belledonne, Pelvoux and Aar massifs and in the Gotthard nappe. During strike-slip movements in the Maritime Alps (including the Argentera) and reverse faulting in the external massifs, fissure monazite domain ages as old as 21.7 ± 0.4 Ma developed in the eastern Tauern Window (Ricchi et al., 2020a). These fissures are related to uplift of the Tauern Window in combination with strike-slip movement (e.g., Rosenberg et al., 2018). This deformation is related to the Dolomite indenter tectonics, which may have ceased at ~ 15 Ma, consistent with the fissure monazite record of the eastern Tauern Window (Ricchi et al., 2020a). The geodynamically different movement of the Dolomite indenter (eastern Adria) versus the slightly different timing and deformation in the western part of Adria is consistent with paleogeographic reconstructions proposed by van Hinsbergen et. al. (2020).
A paleogeographic reconstruction at 20 Ma (Fig. 7) from Handy et. al. (2010) displays the tectonic situation and the location where fissure formation occurred. The stress field and related fissure orientations were changing to strike-slip movements at ~ 12 Ma, which will be discussed in the next section.
~ 12–5 Ma
At about 12 Ma (Fig. 8) strike-slip faults formed along the northern boundary of the Lepontine dome (Bergemann et al., 2020), along the boundaries and in sub-parallel fault zones within the external massifs and its activity has been dated with monazite (Bergemann et al., 2019; Berger et al., 2013; Gasquet et al., 2010; Grand’Homme et al., 2016; Ricchi et al., 2019). The strike-slip movements are accompanied with normal faulting (i.e. Simplon Fault; Mancktelow, 1992; Fig. 8). The kinematics of large system like the Simplon and the Rhone-Simplon faults produce veins (Haertel & Herwegh, 2014). Fissure and cleft monazites record ages as young as 5 Ma (Bergemann et al., 2020; Fig. 5) related to the strike-slip movements along the lateral ramp. Comparable young ages are found in the Aar Massif (Bergemann et al., 2017; Berger et al., 2013), along the Rhone-Simplon fault in the Lepontine Dome and the Mont Blanc/Aiguilles Rouges massifs (Bergemann et al., 2019, 2020) and in the Belledonne Massif (Gasquet et al., 2010; Grand’Homme et al., 2016). Monazite growth appears to have ceased around that time, most likely due to penetrating meteoric water giving way to very low grade cleft mineral crystallization such as zeolithes and clay minerals (e.g., Mullis et al., 2001a, 2001b; Sharp et al., 2005; Weisenberger & Bucher, 2010; Weisenberger et al., 2012).
Muscovite new growth in strike-slip faults (Schneider et al., 2013) and fissure monazite domain ages (Ricchi et al., 2020a) indicate an episodic reactivation of the strike-slip faults between ~ 12 and 9 Ma in the central and western Tauern Window (Fig. 8), probably coeval with activity along the Brenner detachment fault. Fissures that formed during these different strike-slip movements show vertical orientation (Fig. 4), roughly parallel to the older fissure generation. Faults active at 12 and 9 Ma are shown in Fig. 8.
6.3 Fissures and the σ3 orientation
By interpreting fissures as mode 1 fractures (e.g., Twiss & Moores, 2007), the measured orientations of fissures give additional information about the stress field during their formation. However, from fissure orientation only no related movement can be inferred. Therefore, the fissure data give not the same quality of information as palaeostress analysis using additionally lineations on faults or seismic data using beach-ball analysis. Moreover, the local dynamics of cleft opening may include reorientation of the local relationship of preexisting fractures and stress field. The latter can for example be recognized by sigmoidal-shaped veins or sigmoidal ending of clefts. Such differences can locally be recognized by detail field work, but the most frequent clefts are large, more or less straight openings, developing at least initially during mode 1 fracturing.
A compilation of best estimates for the σ3 axes of palaeostress orientations based on brittle structures was provided by Bertrand and Sue (2017) and is shown in Fig. 4 together with the fissure orientation. The orientation of fissures, that formed in the 12–5 Ma range in the Lepontine dome and in the external massifs, except Argentera, are generally in good agreement with the inferred σ3 directions of Bertrand and Sue (2017) (Fig. 4). These fissures are mainly related to dextral strike-slip faulting. This is also true for the sinistral strike-slip related fissures in the Tauern Window and the estimated stress field (Bertrand et al., 2015). Stress ellipsoid orientation obtained from earthquake analysis is also comparable with this late faulting (e.g., Fréchet et al., 2011). However, the Plio-Quaternary σ3 directions of Bertrand and Sue (2017) in the Western Alps are not represented in our fissure orientation dataset (Fig. 4). The inferred Plio-Quaternary σ3 directions are influenced by the exhumation and topographic evolution of the mountain belt. In contrast to missing insights in the youngest history, fissure orientations have the potential to preserve older stress fields (Fig. 4). Combining the presented fissure orientations of > 25 Ma old fissures in the Austroalpine and the high pressure units of the Western Alps, the data show that stress fields of different age may be similar in orientation.
6.4 Fluid evolution
In most cases, the initial fissure-filling fluid is of metamorphic origin and the composition is rock-buffered (Heijboer et al., 2003a; Mangenot et al., 2021; Mullis, 1996; Mullis & De Capitani, 2000; Mullis & Tarantola, 2015; Mullis et al., 1994, 2017; Poty, 1969; Tarantola et al., 2007, 2009). This fluid composition and physical conditions (P/T) determine the habit of quartz (Fig. 3; Mullis, 1991; Mullis et al., 1994), the dominating mineral in most fissures. On the other hand, the quartz habit allows for a fluid zone assessment where fluid inclusion data are lacking. The later fluid evolution in the same region may be different. For example, a fissure may become overprinted, as has been shown by Bergemann et. al. (2017) in the Aar Massif, where a horizontal fissure that had formed during reverse faulting was later overprinted by strike slip movements. The reopening of the fissure fluid system during a change in the stress field (from reverse faulting to strike-slip faulting) caused chemical disequilibrium within the fissures. In several areas of the saline water zone in the external massifs renewed fissure deformation was associated with localized infiltration of a CO2-rich fluid, causing mineral reactions, fluid unmixing and sceptre quartz (often amethyst) overgrowths on previously crystallized long prismatic or Tessin habit quartz (e.g., Burgsteiner, 2004; Hossfeld, 1977; Mullis, 1991, 1996; Mullis & De Capitani, 1997; Mullis et al., 1994; Poty, 1969; Stalder et al., 1998).
More generalized, with decreasing temperature different types of fluid evolution have been observed (Mullis et al., 1994): (1) Decrease in the amount of volatiles and dissolved salt at an increase of bulk fluid inclusion density; (2) Episodes of volatile (CH4 or CO2) enrichment leading to formation of sceptre and ‘window-shaped’ quartz (amethyst overgrowth), and (3) Strong salt enrichment due to attribution of channelized fluids derived from evaporates.
At temperatures below ~ 300 °C, meteoric water may penetrate some fissure systems (Bergemann et al., 2017; Bucher & Weisenberger, 2013; Heijboer et al., 2003b, 2006; Mullis, 2011; Mullis et al., 1994, 2001a, 2001b; Sharp et al., 2005; Wolf & Mullis, 2012; Wolf et al., 2015) and dilute the fissure-filling fluid. This is commonly associated with a late growth of zeolite minerals in the fissures due to changes in fluid composition (e.g., Weisenberger & Bucher, 2010).
The combination of fluid inclusion data, crystal habit observations, isotope dating and structural data illustrate the complex and long lasting process for fissure/cleft formation in the Alps. Whereas the fluid history and the related mass transfer is locally controlled and depending on the composition of the country rock, the structural setting and timing of the fissures will give insights into the evolution of the Alps. Where fluid inclusion data are lacking, the quartz habit may be used to estimate quartz formation temperature and fluid type (Fig. 3).
The concentration of open fissures and clefts is most elevated in the Tauern Window, the Lepontine Dome and the external massifs, but fissures occur locally in all parts of the Alps (Fig. 1). The unequal distribution of fissures may be related to metamorphic grade, the connected rheology, the amount and distribution of deformation, and fluid availability. Areas with high amounts of non-localized deformation have little fissure preservation potential due to ongoing overprinting (see for example veins in the southern Lepontine dome).
Our data show that fissure formation occurred in different regions of the Alps at different times:
In the Austroalpine region fissure mineral formation is constrained between 90 and 70 Ma (Bergemann et al., 2018), in association with metamorphic dome formation and shear zone activity during Barrow-type metamorphism overprinting high-pressure metamorphic areas. The ENE orientation of the fissures indicates a SSE–NNW directed extension during exhumation of the Koralpe-Saualpe region.
In the high to ultrahigh pressure region of the Western Alps (and possibly also in corresponding units of the Tauern and Engadine Windows) fissure formation is associated with folding and exhumation of subducted material (e.g., Ceriani et al., 2001; Fügenschuh & Schmid, 2003). At least in the Western Alps this exhumation followed a cool decompression path including backthrusting and normal faulting into the greenschist facies. This led to fissure monazite crystallization between 36 and 30 Ma.
In the Tauern Window and the Lepontine Dome, fissure monazite crystallization occurred in association with dome formation between 22 and 12 Ma. Fissure formation started at > 22 Ma in the Tauern, and somewhat later in the Lepontine dome (Fig. 6). Reverse faulting and related large fissure formations in the external massifs started also at ~ 22 Ma. Fissure formation in association with shear zone activity occurred coevally in the Argentera Massif and in the Briançonnais zone. The fissure formation in the Argentera Massif and in the Briançonnais zone are linked to dextral strike-slip movements lasting at least until 14.4 ± 0.5 Ma (Ricchi et al., 2020b).
Strike-slip movements starting at ~ 12 Ma and lasting until today were producing vertical fissures and clefts in different regions of the Alps (Fig. 8). Fissure formation is concentrated (or limited) to regions. Episodic reactivation of strike-slip movements of faults and connected fissures is best documented in the fissure monazite record.
Combining different methods (isotope dating, fluid inclusions, structures) open fissures provide important complementary information about the thermal-, fluid- and geodynamic evolution of the Alps and other orogens. Where fluid inclusion data are lacking, the quartz habit can be used to constrain the fluid type. Fissures are highly concentrated in areas where the brittle/ductile transition is preserved. Some areas with exhumed medium-grade amphibolite facies of higher-grade metamorphism contain either no fissures or completely overprinted fissures described as veins. In areas of missing competence contrast of the material, the brittle–ductile transition may never be reached and fissures are hence rare or completely missing.
Availability of data and materials
All data used are from published papers. Unpublished material is provided in Additional file.
Agard, P., Fournier, M., & Lacombe, O. (2003). Post-nappe brittle extension in the inner Western Alps (Schistes Lustrés) following late ductile exhumation: A record of synextension block rotation. Terra Nova, 15, 306–314.
Allaz, J., Maeder, X., Vannay, J., & Steck, A. (2005). Formation of aluminosilicate-bearing quartz veins in the Simano nappe (Central Alps): Structural, thermobarometric and oxygen isotope constraints. Swiss Journal of Geosciences, 85, 191–214.
Ayers, J. C., Miller, C., Gorisch, B., & Milleman, J. (1999). Textural development of monazite during high-grade metamorphism; hydrothermal growth kinetics, with implications for U, Th–Pb geochronology. American Mineralogist, 84, 1766–1780.
Bambauer, H. U., Brunner, G. O., & Laves, F. (1961). Beobachtungen über Lamellenbau an Bergkristallen. Zeitschrift für Kristallographie, 116, 173–181.
Barlier, J. (1974). Rechereches paléothermométriques dans le domaine de Terres Noires subalpines méridionales. Thèse de 3ème cycle, Univ. Paris-Sud (Centre d'Orsay), France.
Beitter, T., Wagner, T., & Markl, G. (2008). Formation of kyanite–quartz veins of the Alpe Sponda, Central Alps, Switzerland: implications for Al transport during regional metamorphism. Contributions to Mineralogy and Petrology, 156, 689–670. https://doi.org/10.1007/s00410-008-0310-4.
Bergemann, C., Gnos, E., Berger, A., Whitehouse, M., Mullis, J., Wehrens, P., Pettke, T., & Janots, E. (2017). Th–Pb ion probe dating of zoned hydrothermal monazite and its implications for repeated shear zone activity: An example from the Central Alps, Switzerland. Tectonics, 36, 671–689.
Bergemann, C. A., Gnos, E., Berger, A., Whitehouse, M. J., Mullis, J., Walter, F., & Bojar, H.-P. (2018). Constraining long-term fault activity in the brittle domain through in situ dating of hydrothermal monazite. Terra Nova, 30, 440–446.
Bergemann, C. A., Gnos, E., Berger, A., Janots, E., & Whitehouse, M. J. (2020). Dating tectonic activity in the Lepontine Dome and Rhône-Siplon Fault regions through hydrothermal monazite-(Ce). Solid Earth, 11, 199–222.
Bergemann, C. A., Gnos, E., & Whitehouse, M. J. (2019). Insights into the tectonic history of the Western Alps through dating of fissure monazite in the Mont Blanc and Aiguilles Rouges Massifs. Tectonophysics, 750, 203–212.
Berger, A., & Bousquet, R. (2008). Subduction-related metamorphism in the Alps: Review of isotopic ages based on petrology and their geodynamic consequences. Geological Society of London Special Publications, 298, 117–144.
Berger, A., Gnos, E., Janots, E., Whitehouse, M., Soom, M., Frei, R., & Waight, T. E. (2013). Dating brittle tectonic movements with cleft monazite: Fluid-rock interaction and formation of REE minerals. Tectonics, 132, 1–14.
Bernard, D. (1978). Microthermométrie des inclusions fluides de cristaux syncinématiques. Applications à la couverture sédimentaire du Nord Pelvoux. Thèse de 3ème cycle, Université scientifique et medicale, Grenoble, 132.
Bertrand, A., Rosenberg, C. L., & Garcia, S. (2015). Fault slip analysis and late exhumation of the Tauern Window, Eastern Alps. Tectonophysics, 649, 1–17.
Bertrand, A., & Sue, C. (2017). Reconciling late faulting over the whole Alpine belt: From structural analysis to geochronological constrains. Swiss Journal of Geociences, 110, 565–580.
Bousquet, R., Oberhänsli, R., Schmid, S. M., Berger, A., Wiederkehr, M., Robert, C., Möller, A., Rosenberg, C., Zeilinger, G., Molli, G., & Koller, F. (2012a). Metamorphic framework of the Alps 1:100’000. . Commission for the Geological Map of the World (CCGM/CGMW).
Bousquet, R., Schmid, S. M., Zeilinger, G., Oberhänsli, R., Rosenberg, C., Molli, G., Robert, C., Wiederkehr, M., & Rossi, P. (2012b). Tectonic framework of the Alps 1:100’000. CCGM/CGMW.
Bucher, K., & Weisenberger, T. (2013). Fluid induced mineral composition adjustments during exhumation: The case of Alpine stilbite. Contributions to Mineralogy and Petrology, 166, 1489–1503.
Burgsteiner, E. (2004). ….wie im Märchen: ein grossartiger Amethyst-Fund im Mörchnerkar/Zillertal. Mineralien-Welt, 2004, 35–37.
Burkhard, M., & Kerrich, R. (1988). Fluid regimes in the deformation of the Helvetic nappes, Switzerland, as inferred from stable isotope data. Contributions to Mineralogy and Petrology, 99, 416–429.
Burri, T., Berger, A., & Engi, M. (2005). Trtiary migmatites in the Cenrtal Alps: Regional distribution, field relations, conditions of formation, and tectonic implications. Schweizerische Mineralogische und Petrographische Mitteilungen, 85, 215–232.
Ceriani, S., Fügenschuh, B., & Schmid, S. M. (2001). Multi-stage thrusting at the Penninic Front in the Western Alps between Mont Blanc and Pelvoux massifs. International Journal of Earth Sciences, 90, 685–702.
Cesare, B., Poletti, E., Boiron, M.-C., & Cathelineau, M. (2001). Alpine metamorphism and veining in the Zentralgneis complex of the SW Tauern Window: A model of fluid-rock interactions based on fluid inclusions. Tectonophysiscs, 336, 121–136.
Cherniak, D. J., Watson, E. B., Grove, M., & Harrison, T. M. (2004). Pb diffusion in monazite: A combined RBS/SIMS study. Geochimica et Cosmochimica Acta, 68, 829–840.
Collombet, M., Thomas, J. C., Chauvin, A., Tricart, P., Bouillin, J. P., & Gratier, J. P. (2002). Counterclockwise rotation of the western Alps since the Oligocene: New insights from paleomagnetic data. Tectonics, 21, 1032.
Corsini, M., Ruffet, G., & Caby, R. (2004). Alpine and late-hercynian geochronological constraints in the Argentera Massif (Western Alps). Eclogae Geologicae Helvetiae, 97, 3–15.
Dewey, J. F., Helman, M. L., Turco, E., Hutton, D. H. W., & Knott, S. D. (1989). Kinematics of the western Mediterranean. In M. P. Coward, D. Dietrich, & R. G. Park (Eds.), Alpine tectonics. (pp. 265–283). Geological Society of London.
Diamond, L. W., & Tarantola, A. (2015). Interpretation of fluid inclusions in quartz deformed by weak ductile shearing: Reconstruction of differential stress magnitudes and pre-deformation fluid properties. Earth and Planetary Science Letters, 417, 107–119.
Engi, M., Bousquet, R., & Berger, A. (2004). Explanatory notes to the map: Metamorphic structure of the Alps, Central Alps. Mitteilungen der Oesterreichischen Mineralogischen Gesellschaft, 149, 157–173.
Fabre, C., Boiron, M.-C., Dubessy, J., Cathelineau, M., & Banks, D. A. (2002). Paleofluid chemistry of a single fluid event: A bulk and in-situ multi-technique analysis (LIBS, Raman spectroscopy) of an Alpine fluid. Chemical Geology, 182, 249–264.
Facenna, C., Becker, T. W., Lucente, F. P., Jolivet, L., & Rosetti, F. (2001). History of subduction and back-arc extension in the Central Mediteranean. Geophysical Journal International, 145, 809–820.
Felix, H. & Mullis, J. (2013). Evolution and composition, temperature and pressure of fluid inclusions through the NEAT Lötschberg base tunnel. In 11th Swiss geoscience meeting, Lausanne, 2013. Abstract.
Fox, M., Herman, F., Willett, S. D., & Schmid, S. M. (2016). The exhumation history of the European Alps inferred from linear inversion of thermochronometric data. American Journal of Science, 316, 505–541.
Fréchet, J., Thouvenot, F., Frogneux, M., Deichmann, N., & Cara, M. (2011). The MW 4.5 Vallorcine (French Alps) earthquake of 8 September 2005 and its complex aftershock sequence. Journal of Seismology, 15, 43–56.
Frey, M., Bucher, K., Frank, E., & Mullis, J. (1980a). Alpine metamorphism along the Geotraverse Basel-Chiasso—A review. Eclogae Geologicae Helvetiae, 73(2), 527–546.
Frey, M., Desmons, J., & Neubauer, F. (1999). The new metamorphic map of the Alps. Schweizerische Mineralogische und Petrographische Mitteilungen, 79, 1–4.
Frey, M., Teichmüller, M., Teichmüller, R., Mullis, J., Künzi, B., Breitschmid, A., Gruner, U., & Schwizer, B. (1980b). Very low-grade metamorphism in external parts of the Central Alps: Illite crystallinity, coal rank and fluid inclusion data. Eclogae Geologicae Helvetiae, 73, 173–203.
Friedlaender, C. (1951). Untersuchung über die Eignung Alpiner Quarze für piezoelektrische Zwecke. Beiträge zur Geologie der Schweiz, geotechnische Serie, 29, 1–98.
Froitzheim, N., Schmid, S. M., & Frey, M. (1996). Mesozoic paleogeography and the timing of eclogite-facies metamorphism in the Alps: A working hypothesis. Eclogae Geologicae Helvetiae, 92, 712–727.
Fügenschuh, B., & Schmid, S. M. (2003). Late stages of deformation and exhumation of an orogen constrained by fission-track data: A case study in the Western Alps. Geological Society of America Bulletin, 115, 1425–1440.
Gansser, A. (1963). Quarzkristalle aus den kolumbianischen Anden (Südamerika). Schweizerische Mineralogische und Petrographische Mitteilungen, 43(1), 91–103.
Gardés, E., Jaoul, O., Montel, J. M., Seydoux-Guillaume, A. M., & Wirth, R. (2006). Pb diffusion in monazite: An experimental study of interdiffusion. Geochimica et Cosmochimica Acta, 70, 2325–2336.
Gardés, E., Montel, J. M., Seydoux-Guillaume, A. M., & Wirth, R. (2007). Pb diffusion in monazite: New constraints from the experimental study of interdiffusion. Geochimica et Cosmochimica Acta, 71, 4036–4043.
Gasquet, D., Bertrand, J.-M., Paquette, J.-L., Lehmann, J., Ratzov, G., De Ascencao Guedes, R., Tiepolo, M., Boullier, A.-M., Scaillet, S., & Nomade, S. (2010). Miocene to Messinian deformation and hydrothermal activity in a pre-Alpine basement massif of the French western Alps: New U–Th–Pb and Argon ages from the Lauzière massif. Bulletin de la Société Géologique de France, 181, 227–241.
Gattacceca, J., Deino, A. L., Rizzo, R., Jones, B., Henry, B., Beaudoin, B., & Vadeboin, F. (2007). Miocene rotation of Sardinia: New paleomagnetic and geochronological constraints and geodynamic implications. Earth and Planetary Science Letters, 258, 359–377.
Glas, M. (1992). Bergkristall - Stein der Weisen und der Wissenschft, extraLapis. (Vol. 3, p. 96). Christian Weise Verlag.
Gnos, E., Janots, E., Berger, A., Whitehouse, M., Walter, F., Pettke, T., & Bergemann, C. (2015). Age of cleft monazites in the eastern Tauern Window: Constraints on crystallization conditions of hydrothermal monazite. Swiss Journal of Geociences, 108, 55–74.
Grand’Homme, A., Janots, E., Bosse, V., Seydoux-Guillaume, A. M., & De Ascenção-Guedes, R. (2016a). Interpretation of U–Th–Pb in-situ ages of hydrothermal monazite-(Ce) and xenotime-(Y): Evidence from large-scale regional study in clefts from the western Alps. Mineralogy and Petrology, 110, 787–807.
Grand’Homme, A., Janots, E., Seydoux-Guillaume, A. M., Guillaume, D., Bosse, V., & Magnin, V. (2016b). Partial resetting of the U–Th–Pb systems in experimentally altered monazite: Nanoscale evidence of incomplete replacement. Geology, 44(6), 431–434. https://doi.org/10.1130/G37770.1.
Haertel, M., & Herwegh, M. (2014). Microfabric memory of vein quartz for strain localization in detachement faults: A case study on the Simplon fault zone. Journal of Structural Geology, 68, 16–32.
Handy, M. R., Schmid, S. M., Bousquet, R., Kissling, E., & Bernoulli, D. (2010). Reconciling plate-tectonic reconstruction of Alpine Tethys with the geological-geophysical record of spreading and subduction in the Alps. Earth-Science Reviews, 102, 121–158.
Hasenberger, K. M. (1996). Flüssigkeitseinschlüsse in alpinen Kluftquarzen aus dem östlichen Tauernfenster. Diploma Thesis, University of Salzburg, 94.
Heijboer, T. C., Mullis, J., & De Capitani, C. (2003a). Prograde and retrograde fluid evolution and vein mineralization from the southern Gotthard Massif, Switzerland. EGS-AGU-EUG Joint Assembly, Abstracts Nice, France (06.–11.04.2003). Geophysical Research Abstracts, 5, 04946.
Heijboer, T. C., Mullis, J. & De Capitani, C. (2006). Fluid-rock interaction in successive veining events from the Fibbia meta-granite of the Gotthard Massif, Switzerland. In 4th Swiss geoscience meeting, Bern.
Heijboer, T. C., Mullis, J., Vennemann, T. & De Capitani, C. (2003b). Fracturing and fluid flow in the External Central Alps during retrograde Alpine metamorphism. In Abstract, first Swiss GEOSCIENCE MEeting, Basel, 28–29 Nov, 2003.
Herwegh, M., Berger, A., Glotzbach, C., Wangenheim, C., Mock, S., Wehrens, P., Baumberger, R., Egli, D., & Kissling, E. (2020). Late stages of continent-continent collision: Timing, kinematic evoluation, and exhumation of the northern Rim (Aar Massif) of the Alps. Earth-Science Reviews, 200, 102959.
Hetherington, C. J., Mullis, J., Graeser, S., & Gieré, R. (2003). Formation of armenite in the Berisal Complex, Simplon Region, Switzerland. Schweizerische Mineralogische und Petrographische Mitteilungen, 83, 243–259.
Hoernes, S., & Friedirchsen, H. (1980). Oxygen and hydrogen isotopic composition of Alpine and Pre-Alpine minerals of the Swiss Central Alps. Contribution to Mineralogy and Petrology, 72, 19–32.
Hossfeld, J. (1977). Die Mineralien des Sterzinger Gebiet. (p. 79). Athesia.
Janots, E., Berger, A., Gnos, E., Whitehouse, M. J., Lewin, E., & Pettke, T. (2012). Constraints on fluid evolution during metamorphism from U–Th–Pb systematics in Alpine hydrothermal monazite. Chemical Geology, 326(327), 61–71.
Janots, E., Grand’Homme, A., Bernet, M., Guillaume, D., Gnos, E., Boiron, M.-C., Rossi, M., Seydoux-Guillaume, A.-M., & De Ascençao Guedes, R. (2019). Geochronological and thermochronometric evidence of unusually hot fluids in an Alpine fissure of Lauzière granite (Belledonne, Western Alps). Solid Earth, 10, 211–223.
Jourdan, A.-L., Vennemann, T. W., Mullis, J., Ramseyer, K., & Spiers, C. J. (2009). Evidence of growth and sector zoning in hydrothermal quartz from Alpine veins. European Journal of Mineralogy, 21, 219–231.
Kandutsch, G. (1989). Die morphologische Einteilung alpiner Zerrkluftquarze und deren Anwendung als Geothermometer im Tauernfenster. Ph.D. thesis, University of Salzburg, 137.
Kandutsch, G., Hasenberger, K., & Kirchner, E. C. (1998). Neue Daten zur Genese alpiner Zerrklüfte. Wissenschaftliche Mitteilungen aus dem Nationalpark Hohe Tauern, 4, 7–17.
Kandutsch, G., & Wachtler, M. (2000). Die Kristallsucher. Ein Gang durch die Jahrmillionen. (Vol. 2, p. 160). Christian Weise Verlag.
Klemm, L., Pettke, T., Graeser, S., Mullis, J., & Kouzmanov, K. (2004). Fluid mixing as the cause of sulphide precipitation at Albrunpass, Binn Valley, Central Alps. Schweizerische Mineralogische und Petrographische Mitteilungen, 84(1/2), 189–212.
Köppel, V., & Grünenfelder, M. (1975). Concordant U–Pb ages of monazite and xenotime from the Central alps and the timing of the high temperature Alpine metamorphism, a preliminary report. Schweizerische Mineralogische und Petrographische Mitteilungen, 55, 129–132.
Kürsteiner, P., Soom, M., & Hofmann, B. (2015). Mineralienfunde im Taminatal SG – 2. Teil. Schweizer Strahler, 2(2015), 13–23.
Kurz, W., & Fritz, H. (2003). Tectonometamorphic evolution of the Australpine Nappe Complex in the Eastern Alps—Consequences for the Eo-Alpine evolution of the Eastern Alps. International Geology Review, 45, 1100–1127.
Leloup, P. H., Arnaud, N., Sobel, E. R., & Lacassin, R. (2005). Alpine thermal and structural evolution of the highest external crystalline massif: The Mont Blanc. Tectonics, 24, TC4002.
Liati, A., & Gebauer, D. (2009). Geochronological evolution of HP metamorphic rocks of the Adula nappe, Central Alps, in pre-Alpine and Alpine subduction cycles. Journal of the Geological Society, 166, 797–810.
Luckscheiter, B., & Morteani, G. (1980). Microthermometrical and chemical studies of fluid inclusions in minerals from Alpine veins from the Penninic rocks of the central and western Tauern window (Austria/Italy). Lithos, 13, 61–77.
Maffione, M., Speranza, F., Faccenna, C., Cascella, A., Vignaroli, G., & Sagnotti, L. (2008). A synchronous Alpine and Corsica-Sardinia rotation. Journal of geophysical Research, 113, B03104.
Mancktelow, N. S. (1992). Neogene lateral extension during convergence in the Central Alps: Evidence from interrrelated faulting and backfolding around the Simplonpass (Switzerland). Tectonophysics, 215, 295–317.
Mangenot, X., Tarantola, A., Mullis, J., Girard, J. P., Le, V. H., & Eiler, J. M. (2021). Geochemistry of clumped isotopologues of CH4 within fluid inclusions in Alpine tectonic quartz fissures. Earth and Planetary Science Letters, 561, 116792. https://doi.org/10.1016/j.epsl.2021.116792.
Manzotti, P., Bosse, V., Pitra, P., Robyr, M., Schiavi, M., & Ballèvre, M. (2018). Exhumation rates in the Gran Paradiso Massif (Western Alps) constrained by in situ U–Th–Pb dating of accessory phases (monazite, allanite and xenotime). Contributions to Mineralogy and Petrology, 173, 24.
Marshall, D., Meisser, N., & Taylor, R. P. (1998a). Fluid inclusion, stable isotope and Ar–Ar evidence for the age and origin of gold-bearing quartz veins at Mont Chemin, Switzerland. Mineralogy and Petrology, 62, 147–165.
Marshall, D., Pfeifer, H. R., Hunziker, J. C., & Kirschner, D. (1998b). A pressure-temperature-time path for the NE Mont Blanc massif: Fluid-inclusion, isotopic and thermobarometric evidence. European Journal of Mineralogy, 10, 1227–1240.
Martin, R., Mullis, J., Nungaesser, W., & Galetti, G. (1982). La whewellite des terrres noires de la Drôme (France). Schweizerische Mineralogische und Petrographische Mitteilungen, 62, 1–13.
Miron, G. D., Wagner, T., Wälle, M., & Heinrich, C. A. (2013). Major and trace element composition and pressure-temperature evolution of rock-buffered fluids in low-grade accretionary-wedge metasediments, Central Alps. Contributions to Mineralogy and Petrology, 165, 981–1008.
Mullis, J. (1974). Zur Entstehungsgeschichte der alpinen Zerklüfte. Mineralienfreund, 6(1974), 77–88.
Mullis, J. (1975). Growth conditions of quartz crystals from the Val d’Illiez (Valais, Switzerland). Schweizerische Mineralogische und Petrographische Mitteilungen, 55, 419–430.
Mullis, J. (1976a). Die Quarzkristalle des Val d’Illiez - Zeugen spätalpiner Bewegungen. Eclogae Geologicae Helvetiae, 69, 343–357.
Mullis, J. (1976b). Das Wachstumsmilieu der Quarzkristalle im Val d’Illiez (Wallis, Schweiz). Schweizerische Mineralogische und Petrographische Mitteilungen, 56, 219–268.
Mullis, J. (1979). The system methane-water as a geological thermometer and barometer from the external part of the Central Alps. Bulletin de Minéralogie, 102, 526–536.
Mullis, J. (1980). Quarz-Kristalle aus dem Maderanertal. Lapis, 5(5), 19–21.
Mullis, J. (1983). Einschlüsse in Quarzkristallen der Schweizer Alpen und ihre mineralogisch-geologische Bedeutung. Bulletin de la Société Fribourgoise des Sciences Naturelles, 72, 127–161.
Mullis, J. (1987). Fluid inclusion studies during very-low grade metamorphism. In M. Frey (Ed.), Low temperature metamorphism. (pp. 162–199). Blackie.
Mullis, J. (1988). Erdöl- und erdgasführende Quarzkristalle aus den nördlichen Kalkalpen der Schweiz. Mineralienfreund, 4(1988), 61–67.
Mullis, J. (1991). Bergkristall. Schweizer Strahler, 9(3), 127–161.
Mullis, J. (1995). Genesis of Alpine fissure minerals. Leica Wetzlar, Scientific and Technical Information, XI(2), 55–64.
Mullis, J. (1996). P-T-t path of quartz formation in extensional veins of the Central Alps. Schweizerische Mineralogische und Petographische Mitteilungen, 76, 159–164.
Mullis, J. (2011). Entstehung alpiner Zerrklüfte und Kluftminerale im Gotthard-Basistunnel, Abschnitt Amsteg-Sedrun und im Zugangs- und Kabelstollen von Amsteg. In P. Amacher & Th. Schüpbach (Eds.), NEAT-Mineralien, Kristall-Schätze tief im Berg. (pp. 194–229). Verlag GEO-Uri GMBH. ISBN 978-3-033-03111-1.
Mullis, J., Abart, R. & Vennemann, T. (2003). Fluid regimes along the Glarus overthrust and their possible impacts on thrusting and calc-mylonite formation. In First Swiss geoscience meeting, Basel, 28–29 Nov, 2003. Abstract Volume.
Mullis, J. & De Capitani, C. (1997). Modelling of water-rock interaction for an Alpine fissure in the Central Alps. In European current research on fluid inclusions (ECROFI-XIV), Nancy, France, 27–29 June, 1997, Extended Abstracts’ Volume.
Mullis, J. & De Capitani, C. (2000). Modelling of water-rock interaction for an extensional vein in the Central Alps. Swiss Society for Mineralogy and Petrography. In Annual meeting in Winterthur, 12.10.2000. Program and Abstracts.
Mullis, J., Dubessy, J., Poty, B., & O’Neil, J. (1994). Fluid regimes during late stages of a continental collision: Physical, chemical, and stable isotope measurements of fluid inclusions in fissure quartz from a geotraverse through the Central Alps, Switzerland. Geochimica et Cosmochimica Acta, 58, 2239–2267.
Mullis, J., Ferreiro-Mählmann, R., & Wolf, M. (2017). Fluid inclusion microthermometry to calibrte vitrinite reflectance (between 50 and 270 °C), illite Kübler-Index data and the diagenesis/anchizone boundary in the external part of the Central Alps. Applied Clay Science, 143, 307–319.
Mullis, J., Klappenbach, K., & Oberhänsli, R. (2001). Kronleuchter aus Bergristall. Schweizer Strahler, 1, 4–8.
Mullis, J., Poty, B., & Leroy, J. (1973). Nouvelles observations sur les inclusions à méthane des quartz du Val d’Illiez, Valais (Suisse). Comptes Rendues de l’Académie de Science de Paris, 277(Série D), 813–816.
Mullis, J., Rahn, M., Schwer, P., De Capitani, Ch., Stern, W., & Frey, M. (2002). Correlation of fluid inclusion temperatures with illite “crystallinity” data and clay mineral chemistry in sedimentary rocks from the external part of the Central Alps. Schweizerische Mineralogische und Petrographische Mitteilungen, 82, 325–340.
Mullis, J., & Ramseyer, K. (1996). Wachstumskontrollierter Aluminiumeinbau in Kluftquarzen der Zentralalpen. Mitteilungen der Österreichischen Mineralogischen Gesellschaft, 1451, 160–161.
Mullis, J. & Tarantola, A. (2015). PVTX evolution and re-equilibration of prograde and retrograde fluid inclusions in diagenetic and metamorphic rocks, Central Alps, Switzerland. In European current research on fluid inclusions (ECROFI-XXIII), Leeds, UK, 27–29 June, 2015, Extended Abstracts’ Volume.
Mullis, J., Vennemann, T., & O’Neil, J. (2001). Deep percolating meteoric waters in the Central Alps. (p. 279). European Union Of Geosciences.
Mullis, J. & Wolf M. (2013). Retrograde evolution of paleo- to recent fluids and their impact on mineral precipitation in the Gotthard base tunnel between Amsteg and Sedrun, Sitzerland. In Abstract, 11th Swiss geoscience meeting, Lausanne, 2013.
Niedermayr, G. (1992). Alpine Kluftmineralisationen im Pohorje in Slowenien. Geologija, 35, 207–223.
Niedermayr, G. (1993). Alpine Kluftmineralisationen im Nationalpark Hohe Tauern und ihre Beziehung zur alpidischen Metamorphose. Wissenschaftliche Mitteilungen aus dem Nationalpark Hohe Tauern, 1, 149–168.
Niedermayr, G., Mullis, J., Niedermayr, E., & Schramm, J.-M. (1984). Zur Anchimetamorphose permo-skythischer Sedimentgesteine im westlichen Drauzug, Kärnten - Osttirol (Österreich). Geologische Rundschau, 73(1), 207–221.
Oberhänsli, R., Bousquet, R., Engi, M., Goffé, B., Gosso, G., Handy, M. R., Hoeck, V., Koller, F., Lardeaux, J. M., Polin, J.-M., Rossi, P., Schuster, R., Schwartz, S. & Spalla, M. I. (2004). Metamorphic structure of the Alps. Explanatory note to the "Metamorphic structure of the Alps", Comission for the geological Map of the World, Paris.
Peretti, A., Bucher, I., & Steiger, R. H. (1981). Rb-Sr-Alter von Kluftmineralien im südlichen Gotthardmassif. Schweizerische Mineralogische und Petrographische Mitteilungen, 61, 360–361.
Pfiffner, O. A. (2011). Explanatory notes to the structural map of the Helvetic Zone of the Swiss Alps, including Vorarlberg (Austria) and Haute Savoie (France). Geological Special Map 128. Swiss Geological Survey, swisstopo, Bern.
Pfiffner, O. A. (2015). Geologie de Alpen. (p. 397). Haupt Verlag.
Piccoli, G. C., Maletto, G., Bosio, P., & Lombardo, B. (2007). Minerali del Piemonte et della Valle d’Aosta. (p. 622). Amici del Museo F.
Pleuger, J., Mancktelow, N., Zwingmann, H., & Manser, M. (2012). K–Ar dating of synkinematic clay gauges from Neoalpine faults of the Central, Western and Eastern Alps. Tectonophysics, 550–553, 1–16.
Poty, B. (1969). La croissance des cristaux de quartz dans les filons sur l’exemple du filon de La Gardette (Bourg d’Oisans) et du Massif de Mont-Blanc. Science de la Terre, Mémoire, 17, 1–162.
Poty, B., Asselborn, E., Bayle, L.-D., Boël, D., Bouiller, A.-M., Buvaz, P., Cathelineau, M., Dumont, T., Fiat, D., Fournier, E., Francois, B., Guillot, S., Mullis, J., Salvetti, A. & Wauquiez, L. (2018). Merveileux minéraux des musées de Chamonix-Mont-Blanc et du Bourg-d' Oisans. Editions du Piat. ISBN 978-2-917198-38-4. p 152.
Poty, B., Mullis, J., & Cathelineau, M. (2007). Musée des cristaux: Espace Tairraz. (p. 28). Chamonix-Mont-Blanc.
Poty, B. P., & Stalder, H. A. (1970). Kryometrische Bestimmungen der Salz- und Gasgehalte eingeschlossener Lösungen in Quarzkristallen aus Zerrklüften der Schweizer Alpen. Schweizerische Mineralogische und Petrographische Mitteilungen, 50, 141–154.
Poty, B. P., Stalder, H.-A., & Weisbrod, A. M. (1974). Fluid inclusion studies in quartz from fissures of western and central Alps. Schweizerische Mineralogische und Petraphische Mitteilungen, 54, 717–752.
Proce, M., Mullis, J., Antognini, A. & Franz, L. (2015). Fluid investigation on T-max and retrograde inclusions in quartz from the southern part of the Gotthard base tunnel, Central Alps. In 13th Swiss geoscience meeting, Basel, 2015, p 5.3.
Purdy, J. W., & Stalder, H. A. (1973). K–Ar ages of fissure minerals from the Swiss Alps. Schweizerische Mineralogische und Petraphische Mitteilungen, 53, 79–98.
Rahn, M., Mullis, J., Erdelbrock, K., & Frey, M. (1995). Alpine metamorphism in the North Helvetic Flysch of the Glalrus Alps, Switzerland. Eclogae geologicae Helvetiae, 88(1), 157–178.
Ramseyer, K., & Mullis, J. (1990). Factors influencing short-lived blue cathodoluminescence of a-quartz. American Mineralogist, 75, 791–800.
Rauchenstein-Martinek, K. (2014). Metamorphic fluid history along a cross section through the central Alps: Constraints from LA-ICPMS analysis of fluid inclusions and Ar–Ar geochronology. (p. 157). ETH Zürich.
Rauchenstein-Martinek, K., Wagner, T., Wälle, M., Heinrich, C. A., & Arlt, T. (2016). Chemical evolution of metamorphic fluids in the Central Alps, Switzerland: Insights from LA-ICPMS analysis of fluid inclusions. Geofluids, 16, 877–908.
Repina, S. A. (2010). Zoning and sectoriality of the florencite and xenotime group minerals from quartz veins, the Subpolar Urals. Geology of Ore Deposits, 52, 821–836.
Ricchi, E., Bergemann, C., Gnos, E., Berger, A., Rubatto, D., Whitehouse, M., & Walter, F. (2020a). Cenozoic deformation in the Tauern Window (Eastern Alps, Austria) constrained by in-situ Th–Pb dating of fissure monazite. Solid Earth, 11, 437–467. https://doi.org/10.5194/se-11-437-2020.
Ricchi, E., Bergemann, C., Gnos, E., Rubatto, D., & Whitehouse, M. (2019). Constraining deformation phases in the Aar Massif and the Gotthard Nappe (Switzerland) using Th–Pb crystallization ages of fissure monazite-(Ce). Lithos, 242–243, 223–238.
Ricchi, E., Gnos, E., Rubatto, D., Whitehouse, M., & Pettke, T. (2020b). Ion microprobe dating of fissure monazite in the Western Alps: Insights from the Argentera Massif and the Piemontais and Briançonnais Zones. Swiss Journal of Geosciences, 113, 15. https://doi.org/10.1186/s00015-20-00365-3.
Rolland, Y., Rossi, M., Cox, S. F., Corsini, M., Mancktelow, N., Pennachioni, G., Fornari, M., & Bouiller, A. M. (2008). 40Ar/39Ar dating of ynkinematic white mica; insights from fluid-rock reaction in low-grade shear zones (Mont Blanc Massif) and constraints on timing of deformation in the NW external Alps. In C. Wibberly, W. Kurtz, J. Imber, R. E. Hoisworth, & C. Collettini (Eds.), The internal structure of fault zones: Implications for mechanical and fluid-flow properties. (pp. 293–315). Geological Society of London.
Rosenberg, C. L., & Berger, A. (2009). On the causes and modes of exhumation and lateral growth of the Alps. Tectonics, 28, TC6001. https://doi.org/10.1029/2008TC002442.
Rosenberg, C. L., Berger, A., Bellahsen, N., & Bousquet, R. (2015). Relating orogen width to shortening, erosion, and exhumation during Alpine collision. Tectonics, 34, 1306–1328.
Rosenberg, C. L., Schneider, S., Scharf, A., Betrand, A., Hammerschmidt, K., Rabaute, A., & Brun, J.-P. (2018). Relating collisional kinematics to exhumation processes in the Eastern Alps. Earth Science Reviews, 176, 311–344.
Rossi, M., & Rolland, Y. (2014). Stable isotope and Ar/Ar evidence of prolonged multi-scale fluid flow during exhumation of orogenic crust: Example from the Mont Blanc nd aar massifs (NW Alps). Tectonics. https://doi.org/10.1002/2013TC003438.
Rykart, R. (1995). Quarz-Monographie. (p. 461). Ott Verlag.
Sanchez, G., Rolland, Y., Schneider, J., Corsini, M., Oliot, E., Goncalves, P., Verati, C., Lardeaux, J.-M., & Marquer, D. (2011). Dating low-temperature deformation by 40Ar/39Ar on white mica, insights from the Argentera-Mercantour Massif (SW Alps). Lithos, 125, 521–536.
Satir, M. (1975). Die Entwicklungsgeschichte der westlichen Hohen Tauern und der südlichen Ötztalmasse auf Grund radiometrischer Altersbestimmungen. Memorie degli Istituti di Geologia e Mineralogia dell’Università di Padova, 30, 1–84.
Schenker, F. L., Schmalholz, S. M., Moulas, E., Pleuger, J., Baumgartner, L. P., Podladchikov, Y., Vrijmoed, J., Buchs, N., & Müntener, O. (2015). Current challenges for explaining (ultra)high-pressure tectonism in the Pennine domain of the Central and Western Alps. Journal of metamorphic Geology, 33, 869–886.
Schmid, S. M., Aebli, H. R., Heller, F., & Zingg, A. A. (1989). The role of the periadriatic line in the tectonic evolution of the Alps. Geological Society of London, Special Publication, 45, 153–171.
Schmid, S. M., Fügenschuh, B., Kissling, E., & Schuster, R. (2004). Tectonic map and overall architecture of the Alpine orogen. Eclogae Geologicae Helvetiae, 97, 93–117.
Schmid, S. M., Kissling, E., Diehl, T., van Hinsbergen, D. J. J., & Molli, G. (2017). Ivrea mantle wedge, arc of the Western Alps, and kinematic evolution of the Alps-Apennines orogenic system. Swiss Journal of Geosciences, 110, 581–612. https://doi.org/10.1007/s00015-016-0237-0.
Schmidt, D., Schmidt, S. T., Mullis, J., Ferreiro Mählmann, R., & Frey, M. (1997). Very low grade metamorphism of the Taveyanne formation of western Switzerland. Contributions to Mineralogy and Petrology, 129, 385–403.
Schneider, S., Hammerschmied, K., & Rosenberg, C. L. (2013). Dating the longevity of ductile shear zones: Insights from 40Ar/39Ar in situ analysis. Earth and Planetary Science Letters, 369, 43–58.
Schönborn, G. (1992). Alpine tectonic and kinematic models of the central Southern Alps. (pp. 229–393). Memorie degli Istituti di Geologia e Mineralogia dell’ Università di Padova.
Schuster, R. (2015). Zur Geologie der Ostalpen. Abhandlungen der Geologischen Bundes-Anstalt, 64, 143–165.
Schuster, R., Koller, F., Hoeck, V., Hoinkes, G., & Bousquet, R. (2004). Explanatory notes to the map Metamorphic structure of the Alps. Mitteilungen der österreichischen mineralogischen Gesellschaft, 149, 175–199.
Schuster, R., Kurz, W., & Fritz, H. (2013). Introduction to the geology of the Eastern Alps. Berichte der Geologischen Bundes-Anstalt Wien, 99, 121–133.
Seydoux-Guillaume, A. M., Montel, J.-M., Bingen, B., Bosse, V., de Perseval, P., Paquette, J.-L., Janots, E., & Wirth, R. (2012). Low-temperature alteration of monazite: Fluid mediated coupled dissolution-precipitation, irradiation damage, and disturbance of the U–Pb and Th–Pb chronometers. Chemical Geology, 330–331, 140–158.
Sharp, Z. D., Masson, H., & Luccini, R. (2005). Stable isotope geochemistry and formation mechanisms of quartz veins; extreme paleoaltitudes of the Centrals Alps in the Neogene. American Journal of Science, 305, 187–219.
Soom, M. (1986). Geologie und Petrographie von Ausserberg (VS) - Kluftmineralien am Südwestrand des Aarmassivs. (p. 129). University of Bern.
Stalder, H. A., Sicher, V., & Lussmann, L. (1980). Die Mineralien des Gotthardbahntunnels und des Gotthardstrassentunnels N2. (p. 160). REPOF AG.
Stalder, H.-A., & Touray, J. (1970). Fensterquarze mit Methan-Einschlüssen aus dem westlichen Teil der schweizerischen Kalkalpen. Schweizerische Mineralogische und Petrographische Mitteilungen, 50, 109–130.
Stalder, H.-A., Wagner, A., Graeser, S., & Stuker, P. (1998). Mineralienlexikon der Schweiz. (p. 579). Wepf.
Stampfli, G., Mosar, J., Marquer, D., Marchant, R., Baudin, T., & Borel, G. D. (1998). Subduction and obduction processes in the Swiss Alps. Tectonophysics, 296, 159–204.
Steck, A. (1968). Die alpidischen Strukturen in den Zentralen Aaregraniten des westlichen Aarmassivs. Eclogae Geologicae Helvetiae, 61, 19–48.
Tarantola, A., Mullis, J., Guillaume, D., Dubessy, J., De Capitani, C., & Abdelmoula, M. (2009). Oxidation of CH4 to CO2 and H2O by chloritization of detrital biotite at °C in the external part of the Central Alps, Switzerland. Lithos, 112, 497–510.
Tarantola, A., Mullis, J., Vennenmann, T., Dubessy, J., & De Capitani, C. (2007). Oxidation of methane at the CH4/H2O-(CO2) transition zone in the external part of the Central Alps, Switzerland: Evidence from stable isotope investigations. Chemical Geology, 237, 329–357.
Thomas, J. C., Claudel, M. E., Collombet, M., Tricart, P., Chauvin, A., & Dumont, T. (1999). First paleomagnetic data from the sedimentary cover of the French penninic Alps: Evidence for Tertiary counterclockwise rotations in the western Alps. Earth and Planetary Science Letters, 171, 561–574.
Thöni, M. (1981). Degree and evolution of the Alpine metamorphism in the Austroalpine Unit W of the Hohe Tauern in the light of K/Ar and Rb/Sr age determinations on micas". Jahrbuch der geologischen Bundesanstalt, 124, 111–174.
Thöni, M. (1999). A review of geochronological data from the Eastern Alps. Schweizerische Mineralogische und Petrographische Mitteilungen, 79, 209–230.
Touray, J., Vogler, M., & Stalder, H.-A. (1970). Inclusions à hydrocarbures liquifiés dans les quartz de Zingel/Seewen (Suisse). Schweizerische Mineralogische und Petrographische Mitteilungen, 50, 131–139.
Touret, J. (1980). Le métamorphisme régional: régime des fluides et grilles pétrogénétiques. Mémoire hors série, Société de Géologie de France (Livre Jubilaire 150 ans), 10, 63–70.
Twiss, R. J., & Moores, E. M. (2007). Structural geology. (p. 752). Freeman and Company.
van Hinsbergen, D. J. J., Torsvik, T. H., Schmid, S. M., Maţenco, L. C., Maffione, M., Vissers, R. L. M., Gürer, D., & Spakman, W. (2020). Orogenic architecture of the Mediterranean region and kinematic reconstruction of its tectonic evolution since the Triassic. Gondwana Research, 81, 79–229. https://doi.org/10.1016/j.gr.2019.07.009.
Vernon, A. J., van der Beek, P. A., Sinclair, H. D., & Rahn, M. K. (2008). Increase in Late Neogene denudation of the European Alps confirmed by analysis of a fission-track thermochronology database. Earth and Planetary Letters, 270, 316–329.
Wachtler, M., & Kandutsch, G. (2000). Die Kristallsucher. Auf der Suche nach den verborgenen Schätzen. (Vol. 1, p. 160). Christian Weise Verlag.
Wagner, A., Frey, M., Quadrio, F., Schwartzkopf, J., & Stalder, H. A. (1972). Die Mineralienfundstellen von Camperio und Campo Blenio, Kanton Tessin. Jahrbuch des Naturhistorischen Museum Bern, 1969–1971, 277–360.
Wagreich, M. (1995). Subduction tectonic erosion and late Cretaceous subsidence along the northern Austroalpine margin (Eastern Alps, Austria). Tectonophysics, 242, 63–78.
Weisenberger, T., & Bucher, K. (2010). Zeolites in fissures of granites and gneisses of the Central Alps. Journal of Metamorphic Geology, 28, 825–847.
Weisenberger, T., & Bucher, K. (2011). Mass transfer and porosity evolution during low temperature water-rock interaction in gneiss of the Simano nappe: Arvigo, Val Calanca, Swiss Alps. Contributions to Mineralogy and Petrology, 162, 61–81.
Weisenberger, T. B., Rahn, M., van der Lelij, R., Spikings, R. A., & Bucher, K. (2012). Timing of low-temperature mineral formation during exhumation and cooling in the Central Alps, Switzerland. Earth and Planetary Science, Letters, 327–328, 1–8.
Weninger, H. (1981). Mikrothermometrische Untersuchungen an ostalpinen Lagerstätten. Tschermaks Mineralogische und Petrographische Mitteilungen, 29, 127–149.
Wiederkehr, M., Bousquet, R., Schmid, S. M., & Berger, A. (2008). From subduction to collision: Thermal overprint of HP/LT meta-sediments in the north-eastern Lepontine Dome (Swiss Alps) and consequences regarding the tectono-metamorphic evolution of the Alpine orogenic wedge. Swiss Journal of Geosciences, 101, 127–155.
Wolf, M. & Mullis, J. (2012). Retrograde fluid evolution and its impact on mineral precipitation. An example from an Alpine fissure of the Gotthard rail base tunnel between Amsteg and Sedrun, external part of the Central Alps. In 10th Swiss geoscience Meeting, Bern, 2012. p 3.11.
Wolf, M., Mullis, J., Pettke, T., Franz, L. & Vennemann T. (2015). Fluid evolution and mass transfer in the Gotthard Base Tunnel. In: 13th Swiss geoscience meeting, Lausanne, Abstract.
Yardley, B. W. D. (1983). Quartz veins and devolatilization during metamorphism. Journal of the Geological Society of London, 140, 657–663.
Zerlauth, M., Bertrand, A., Rantisch, G., Gross, D., Orther, H., Pomella, H., & Fügenschuh, B. (2015). Thermal history of the westernmost Eastern Alps (Penninic Rhenodanubian Flysch nappes, Helvetic nappes, and subalpine Molasse thrust sheets). International Journal of Earth Sciences, 105, 1525–1547.
Romain Bousquet is thanked for having provided the tectonic map of the Alps in cylindrical-projection for this study and Franz Walter for information about fissure orientations. This work was funded by the Swiss National Science Foundation, projects 200021-143972 and 200020-165513. We thank the two anonymous reviewers and Adrian Pfiffner for their very helpful comments.
This work was funded by the Swiss National Science Foundation, projects 200021-143972 and 200020-165513.
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Additional file 1: Table S1.
Th–U–Pb analyses of monazite by ion microprobe (SwissSIMS). Analyses resulting in unreliable dates (e.g. presence of cracks, affected by Pbc causing high uncertainty) were not considered and are written in italic. Figure S1. Chemical, textural, and geochronological information for fissure monazite grains originally published in Ricchi et. al. (2019). Colour-filled circles on BSE images, correspond to ion probe spot locations. The defined growth domains (A, B, C…) are indicated on BSE images with a distinct colour code (red, orange, blue …). Spot ages considered in the weighted mean age calculations are indicated by colour-filled bars whereas spot ages only considered in the age range are indicated by open bars (bar length representing the spot age plus its 2 σ uncertainty).
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Gnos, E., Mullis, J., Ricchi, E. et al. Episodes of fissure formation in the Alps: connecting quartz fluid inclusion, fissure monazite age, and fissure orientation data. Swiss J Geosci 114, 14 (2021). https://doi.org/10.1186/s00015-021-00391-9
- Fluid inclusions
- Fissure monazite age
- Quartz habit
- Tectonic evolution
- Stress field